一种粘弹性颗粒驱油剂交联网络结构含量测试方法
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中国石油化工股份有限公司胜利油田勘探开发研究院

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TQ 311 DOI

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国家科技重大专项(2025ZD1407100);泰山产业领军人才项目(tscx 202306048);中国石化新领域培育项目(P24016)


A Testing Method for the Content of Cross-linked Network Structure of Viscoelastic Particle Oil Displacement Agent
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Shengli oil field exploration and Development Research Institute

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    摘要:

    粘弹性颗粒驱油剂(PPG和B-PPG)具有部分交联结构和部分支化分子结构,该驱油剂产品中交联网络结构含量对产品的性能有很大影响,是评价该类驱油剂性能的重要特征参数。但是目前尚缺乏针对PPG和B-PPG产品交联网络结构含量的表征方法。本文采用络合剂络合结合液相色谱检测的方法,建立了PPG和B-PPG产品交联网络结构含量的测试方法,具体操作步骤如下:首先对PPG和B-PPG悬浮液中凝胶颗粒进行破碎,然后选择硝酸铝络合剂对PPG和B-PPG悬浮液中线性结构部分干扰去除,结合液相色谱检测络合过程中聚合物色谱峰面积的变化过程,证实了随着硝酸铝用量的增加,出现三段式络合过程,其中第一阶段,聚合物最小色谱峰面积和原始峰面积的比值,即为PPG和B-PPG交联网络结构含量。采用所建立的测试流程,对实际粘弹性颗粒驱油剂样品中交联网络结构的含量进行测试,结果表明,B-PPG的交联网络结构含量在86%左右,PPG的交联网络结构含量在25%左右,B-PPG比PPG具有更多的交联网络结构。

    Abstract:

    In view of the lack of characterization methods for the crosslinked network structure content of viscoelastic particle oil displacement agent products (PPG and B-PPG) at present, the test on the crushing conditions of gel particles in viscoelastic particle oil displacement agent solution confirmed that the crushing extraction process of gel particles was divided into two stages: crushing and trimming, and the best crushing conditions were selected; By conducting interference removal tests on linear structures in viscoelastic particle oil displacement agent solutions, aluminum nitrate was selected as the complexing agent. It was confirmed that with the increase of aluminum nitrate dosage, a three-stage complexation process occurred, and the optimal complexation conditions for completely removing linear structure interference were obtained. Based on the above research, the final testing process for network structure content in viscoelastic particle oil displacement agent samples was obtained. Using the established testing process, the content of cross-linked network structure in actual viscoelastic particle oil displacement agent samples was tested. The results showed that the cross-linked network structure content of B-PPG was about 86%, and that of PPG was about 25%. B-PPG had more cross-linked network structures than PPG.

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  • 收稿日期: 2025-09-18
  • 最后修改日期: 2025-12-25
  • 录用日期: 2026-01-12
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