一株贝莱斯芽孢杆菌的驱油性能及缓蚀行为
DOI:
作者:
作者单位:

1.西安石油大学化学化工学院陕西省油气田环境污染控制与储层保护重点实验室 2.中国石油 长庆油田榆林油气有限公司;3.中国石油 长庆油田(榆林)油气有限公司

作者简介:

通讯作者:

中图分类号:

基金项目:

西安市科技计划“连续管含铜量优化设计及其耐CO2+SRB协同腐蚀机理研究”(24GXFW0077)


The Oil-Displacing Capacity and Corrosion Inhibition Behavior of Bacillus velezensis
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    目的 针对微生物驱油技术(MEOR)中钢材腐蚀加剧现状,从长庆油田采出水中分离得到贝莱斯芽孢杆菌4-19,探究该菌株驱油效率及该菌株对J55钢缓蚀的协同作用机制。方法 通过原油降粘实验、四组分分析及气象色谱分析表征重质组分降解;采用失重法、电化学阻抗谱(EIS)和扫描电镜(SEM)解析缓蚀行为;结合等效电路拟合与X射线能谱(EDS)揭示膜层防护机制。结果 4-19使原油表面张力降低54.5%,3天原油降解率达69%,35℃与40℃原油粘度均有所降低,芳香烃、胶质的相对分子质量分别降低了17.61%和18.60%;J55钢腐蚀速率降低76.23%。EIS显示膜电阻(Rb)提升42.6%,极化电流密度降低76.7%。结论 4-19通过分泌脂肽类生物表面活性剂降解重质组分并竞争性耗氧,形成致密腐蚀产物膜,实现驱油-缓蚀功能耦合,为MEOR现场应用提供新策略。

    Abstract:

    Objective To address the intensified steel corrosion that accompanies microbial enhanced oil recovery (MEOR), a strain of Bacillus velezensis (designated 4-19) was isolated from produced water in the Changqing Oilfield. Its oil-displacement efficiency and the synergistic corrosion-inhibition mechanism on J55 carbon steel were investigated. Methods Crude-oil viscosity reduction, SARA (saturates, aromatics, resins, asphaltenes) fractionation and gas chromatography were employed to characterize the degradation of heavy fractions. Weight-loss measurements, electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM) were used to elucidate the corrosion-inhibition behavior. An equivalent circuit model combined with energy-dispersive X-ray spectroscopy (EDS) was applied to reveal the protective film mechanism. Results Strain 4-19 lowered the crude-oil surface tension by 54.5 % and achieved a 69 % degradation rate within three days. Viscosity at 35 °C and 40 °C was significantly reduced; the relative molecular masses of aromatics and resins decreased by 17.61 % and 18.60 %, respectively. The corrosion rate of J55 steel declined by 76.23 %. EIS indicated that the film resistance (Rb) increased by 42.6 % and the polarization current density decreased by 76.7 %. Conclusion B. velezensis 4-19 secretes lipopeptide biosurfactants that degrade heavy fractions while simultaneously consuming dissolved oxygen, forming a compact corrosion-product film. This coupling of oil recovery and corrosion inhibition offers a novel strategy for field-scale MEOR applications.

    参考文献
    相似文献
    引证文献
引用本文
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期: 2025-08-18
  • 最后修改日期: 2025-08-18
  • 录用日期: 2025-09-28
  • 在线发布日期:
  • 出版日期:
点击这里给我发消息

点击这里给我发消息