低界面张力抗高钙镁减氧空气泡沫体系与性能评价
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陕西延长石油集团有限责任公司研究院

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延长石油科技项目“低界面张力耐盐型纳米颗粒增稳减氧空气泡沫驱技术研究”(ycsy2023ky-B-30-01)


Low interfacial tension anti-high calcium and magnesium oxygen-reducing air foam system and performance evaluation
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1.Research Institute of Shaanxi Yanchang Petroleum Group Co,LTD,Xi'2.'3.an,Shaanxi,China

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    摘要:

    针对延长油田在长6致密油藏高盐地层水(≥120000mg/L),高钙镁(Ca2+≥20000mg/L、Mg2+≥400mg/L),储层非均质强(极差=50)条件下注水驱油效果差,含水高(≥75%),采出程度低(14.7%),油藏手段无法进一步解决开发矛盾,目前泡沫体系无法适应的难题。在模拟油藏环境条件下,采用高温高压泡沫仪综合评价装置、致密储层渗吸系统测试了8种双子型表活剂发泡性能、半衰期、综合泡沫指数,筛选出最佳发泡剂、主剂及其浓度,构筑了一种低界面张力抗钙镁减氧空气泡沫体系。评价了不同温度、Ca2+Mg2+含量、含有率及pH值条件对该体系发泡体积和半衰期的影响,考察了体系非均质储层驱油效果及渗吸效率规律。结果表明0.4% LY-12(双十二烷羟磺酸盐)+0.1% LX-14(十四烷基氨基酸盐)为最佳泡沫体系,温度、Ca2+离子含量、含油率、pH对发泡体积、泡沫半衰期影响大,而受Mg2+含量影响较小,温度≤45℃、Ca2+离子含量≤20000mg/L、含油率≤30%、pH为中性条件下可保证最佳泡沫性能,泡沫综合指数≥12000mL.min,界面张力为6.63×10-2mN/m。当渗透率级差为50时,非均质储层连续泡沫驱较泡沫段塞后续水驱综合驱油效率提高7%,渗透率为0.96×10-3μm2,渗吸效率达42.88%,在低渗储层中具有很好的适应性。

    Abstract:

    In response to the poor water flooding effect, high water cut (≥75%), low recovery rate (14.7%), and the inability of reservoir measures to further resolve the development contradictions in the Chang 6 tight oil reservoir of the Yanchang Oilfield, which is characterized by high salinity formation water (≥120,000 mg/L), high calcium and magnesium (Ca2+≥20,000 mg/L, Mg2+≥400 mg/L), and strong heterogeneity (range = 50), and the current foam systems" inability to adapt to these conditions, eight Gemini surfactants were evaluated for their foaming performance, half-life, and comprehensive foam index under simulated reservoir conditions using a high-temperature and high-pressure foam instrument and a tight reservoir imbibition system. The best foaming agent, main agent, and their concentrations were selected to construct a low interfacial tension, calcium and magnesium resistant, and oxygen-reduced air foam system. The effects of different temperatures, Ca2+ and Mg2+ contents, oil saturation, and pH values on the foaming volume and half-life of the system were evaluated, and the oil displacement efficiency and imbibition efficiency of the system in heterogeneous reservoirs were investigated. The results show that 0.4% LY-12 (dodecyldodecyl hydroxysulfonate) + 0.1% LX-14 (tetradecyl amino acid salt) is the best foam system. Temperature, Ca2+ ion content, oil saturation, and pH have a significant impact on the foaming volume and foam half-life, while the effect of Mg2+ content is relatively small. The best foam performance can be guaranteed under conditions of temperature ≤ 45°C, Ca2+ ion content ≤ 20,000 mg/L, oil saturation ≤ 30%, and neutral pH, with a comprehensive foam index ≥ 12,000 mL.min and an interfacial tension of 6.63×10-2 mN/m. When the permeability contrast is 50, the continuous foam flooding in heterogeneous reservoirs has a 7% higher comprehensive oil displacement efficiency than the foam slug followed by water flooding. When the permeability is 0.96×10-3 μm2, the imbibition efficiency reaches 42.88%, demonstrating good adaptability in low-permeability reservoirs.

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  • 收稿日期: 2025-07-16
  • 最后修改日期: 2025-10-10
  • 录用日期: 2025-10-13
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