高盐油藏硅酸钠对聚合物耐盐性影响
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1.东北石油大学提高油气采收率重点实验室;2.中海石油中国有限公司天津分公司

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国家科技重大专项“渤海双高油田多级窜逸堵调驱一体化技术研究及示范”(2016ZX05058003-010)


The effect of sodium silicate on the salt tolerance of polymers in high salt oil reservoirs
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Key Laboratory of Improving Oil and Gas Recovery Efficiency of NEPU

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    摘要:

    渤海高盐油藏平均渗透率较大,常规聚合物耐盐性较差。为提高常聚合物耐盐性,增加驱油剂增油降水效果,通过黏度和扫描电镜测试,结合物理模拟评价方法,开展了高盐油藏硅酸钠对聚合物耐盐性影响及作用机理研究。结果表明,低矿化度条件下,普通聚合物增黏能力大于抗盐聚合物。随硅酸钠浓度增加,聚合物黏度逐渐增大。在不同的加药方式中,初期“聚合物+硅酸钠”体系黏度低于“硅酸钠+聚合物”,剪切后二者黏度相差不大。聚合物分子为网状结构,无机凝胶为絮状结构,“聚合物+硅酸钠”为骨架更为密集的网状结构。渗流特性实验过程中,相比于单一聚合物溶液,“聚合物+硅酸钠”体系封堵能力增强。随硅酸钠浓度增大,复合体系阻力系数增大,残余阻力系数先增大后减小。研究结果和认识为提升目标油藏含聚调驱剂深部液流转向效果所需药剂配方组成优选和工艺参数优化技术决策提供了实验依据。

    Abstract:

    The average permeability of high salt oil reservoirs in Bohai is relatively high, and conventional polymers have poor salt tolerance. In order to improve the salt resistance of polymers and enhance the oil recovery and precipitation effect of oil displacement agents, the influence and mechanism of sodium silicate on polymer salt resistance in high salt reservoirs were studied through viscosity and scanning electron microscopy tests, combined with physical simulation evaluation methods. The results indicate that under low mineralization conditions, the viscosity increasing ability of ordinary polymers is greater than that of salt resistant polymers. As the concentration of sodium silicate increases, the viscosity of the polymer gradually increases. In different dosing methods, the initial viscosity of the "polymer+sodium silicate" system is lower than that of the "sodium silicate+polymer" system, and the viscosity difference between the two after shearing is not significant. The polymer molecule is a network structure, the inorganic gel is a flocculent structure, and the "polymer+sodium silicate" is a more dense network structure. During the experimental process of permeability characteristics, compared to a single polymer solution, the "polymer+sodium silicate" system showed enhanced sealing ability. As the concentration of sodium silicate increases, the resistance coefficient of the composite system increases, and the residual resistance coefficient first increases and then decreases. The research results and understanding provide experimental basis for the optimization of chemical formula composition and process parameter optimization technology decision-making required to improve the deep liquid flow diversion effect of target reservoirs containing polymer control and flooding agents.

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  • 收稿日期: 2025-07-08
  • 最后修改日期: 2025-08-04
  • 录用日期: 2025-09-12
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