新型微生物聚合物的溶液性能与驱油作用
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1.中国石化胜利油田分公司石油工程技术研究院;2.中国石化胜利油田分公司;3.中国石化胜利油田分公司东辛采油厂

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国家重点研发计划“油田采油生物制剂研发及应用”(编号2022YFC2105200)和中石化攻关项目“新型微生物杂多糖工业化发酵及应用”(编号224129)。汪卫东(1967-),男,教授级高级工程师,本文通讯联系人,中国海洋大学海洋化学专业博士(2004),从事微生物采油技术和微生物处理油田污水技术方面工作,通讯地址:257000 山东省东营市西三路306号胜利油田石油工程技术研究院,E-mail:wangweidong168.slyt@sinopec.com。


Solution Properties and Oil Displacement of A Novel Microbial Polymer
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Shengli Oilfield Company,Sinopec,Dongying

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    摘要:

    常规合成聚合物HPAM耐温抗盐性差,高温高盐下易降解失黏,且残余单体易污染环境。微生物聚合物在极端油藏中面临分子链断裂、絮凝等问题,导致黏度损失,难以满足高温(≥80℃)、高盐(≥30000 mg·L-1)油藏需求。为了适应苛刻油藏环境,开发了一种新型微生物聚合物FH,系统研究了该聚合物的流变特性及其在高温高盐油藏环境下的应用潜力。采用流变仪重点考察温度、盐度、剪切力和pH值等因素对FH聚合物流变性能的影响,同时利用扫描电镜对不同矿化度条件下的FH聚合物微观外貌特征进行了观察,并评价了FH聚合物在极端油藏环境下的长期热稳定性及驱油效果。实验结果显示,FH聚合物和黄原胶均呈现显著的剪切稀化特性,当剪切力解除后,黏度具有可逆性,几乎完全恢复到初始黏度,但是HPAM剪切后,黏度出现不可逆的机械损失现象。FH聚合物在温度(25℃~100℃)、盐度(1000mg·L?1~80000mg·L?1)及pH值(2.0~12.0)范围内,黏度保持稳定,尤其在高矿化度地层水中可以形成密实的网状结构,增强了苛刻油藏环境的耐受性。此外,高温高盐环境中处理40d后,加入含硫有机化合物抗氧剂可以提高FH聚合物的热稳定性,保黏率达73.6%,并在物理模拟驱油实验中表现出良好的驱油效果,提高原油驱替效率13.2%。

    Abstract:

    Conventional synthetic polymer HPAM exhibit poor temperature and salt tolerance, being prone to degradation and viscosity loss under high-temperature and high-salinity conditions, with residual monomers posing environmental risks. Microbial polymers, on the other hand, face challenges such as molecular chain scission and flocculation in extreme reservoir environments, leading to viscosity loss and difficulty in meeting the requirements of high-temperature (≥80°C) and high-salinity (≥30,000 mg·L?1) reservoirs. To address the demands of harsh reservoir conditions, a novel microbial polymer FH has been developed, and its rheological properties as well as its application potential in high-temperature and high-salinity reservoir environments have been systematically studied.The rheological properties of FH polymers were investigated by rheometer using factors such as temperature, salinity, shear force and pH value. Meanwhile, the microscopic appearance characteristics of FH polymers under different mineralization conditions were observed by scanning electron microscopy, and the long-term thermal stability and oil displacement effect of FH polymer in extreme reservoir environments were evaluated.The experimental results showed that both the novel biopolymer FH and xanthan gum have significant shear thinning properties. When the shear force was removed, the viscosity was reversible. But the viscosity of HPAM showed shear loss irreversibly. In the range of temperature (25℃~100℃), salinity (1000 mg·L?1~80000 mg·L?1 and pH (pH2.0 ~ 12.0), the viscosity of the novel microbial polymer remained unchanged basically. Especially in the high salinity of formation water, the novel biopolymer can form dense network structure, which enhances its harsh environmental tolerance. In addition, Under the treatment of high temperature and high salt for 40 days, the addition of sulfur-containing organic compound antioxidant could improve the thermal stability of biopolymer KF, and the adhesion rate reached 73.6%. It also demonstrated excellent oil displacement performance in physical simulation oil displacement experiments, increasing the crude oil displacement efficiency by 13.2%.

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  • 收稿日期: 2025-06-30
  • 最后修改日期: 2025-09-06
  • 录用日期: 2025-09-29
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