硅泥陶粒调堵剂研制及性能评价
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1.中国石油大学北京非常规油气科学技术研究院;2.中国石油辽河油田分公司特种油开发公司

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硅泥调剖技术机理研究与实验 LHYT-TZYKFGS-2024-JS-4491


Development and performance evaluation of silica sludge ceramsite plugging agent
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Unconventional Petroleum Research Institute,China University of Petroleum

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    摘要:

    针对辽河油田注蒸汽热采污水除硅产出硅泥难处理以及稠油注蒸汽开发后期地层亏空、井间汽窜等问题,以废弃硅泥为原料经造粒和烧结处理制得一种耐温高强硅泥陶粒,与聚合物溶液配制成硅泥陶粒调堵剂。通过单因素实验研究了硅泥组分含量、烧结温度对硅泥陶粒抗压强度及表观密度的影响,评价了调堵剂的水热稳定性、悬浮性和封堵性。结果表明,硅泥陶粒在硅泥掺量60%、烧结温度1180℃条件下抗压强度>14 MPa、耐温350℃。对应的调堵剂聚合物中沉降速率≤0.0075 m/min、高温封堵率>82%,可以满足辽河油田稠油热采油藏对于调堵封窜和填充地层亏空的性能要求。同时,通过将采出污水除硅产生的硅泥制备陶粒并进行油田回注利用可减少油田硅泥污染物排放。

    Abstract:

    For the Liaohe oilfield steam injection hot recovery sewage silica sludge output silica sludge is difficult to deal with, and thick oil injection steam development of the latter part of the formation shortfall, inter-well vapor flurry and other issues, waste silica sludge as raw materials through granulation and sintering treatment to produce a temperature-resistant high-strength silica sludge ceramsite, and polymer solution formulated into silica sludge ceramsite plugging agent. The effects of silica sludge component content and sintering temperature on the compressive strength and apparent density of silica sludge ceramsite grains were investigated through one-factor experiments, and the hydrothermal stability, suspension and blocking properties of the plugging agent were evaluated. The results showed that the compressive strength of silica sludge ceramsite was >14 MPa and the temperature resistance was 350℃ under the conditions of 60% silica sludge doping and 1180℃ sintering temperature. Corresponding plugging agent polymer settlement rate ≤ 0.0075 m/min, high temperature plugging rate > 82%, can meet the Liaohe oil field thick oil hot oil recovery reservoir for plugging and sealing tampering and filling the formation deficit performance requirements. At the same time, the silica sludge produced by the silica removal from the extracted wastewater can be used to prepare ceramsite and reinjected back into the oilfield, which can reduce the emission of silica sludge pollutants in the oilfield.

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  • 收稿日期: 2025-06-27
  • 最后修改日期: 2025-07-29
  • 录用日期: 2025-09-19
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