CO?驱蠕虫状胶束泡沫体系构筑及黏弹性研究
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中国石油大学(华东)石油工程学院

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Construction and Viscoelastic Characterization of Wormlike Micellar Foam Systems for CO? Flooding
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School of Petroleum Engineering, China University of Petroleum (East China)

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    摘要:

    在CO2驱油过程中,气窜现象易导致波及体积减小,从而降低采收率。泡沫驱是抑制CO2气窜的有效方法之一。本研究利用阴离子表面活性剂AOS、两性表面活性剂EAB及稳泡剂烷基胺TA构建蠕虫状胶束泡沫体系,并系统研究其黏弹性行为。实验结果表明,当表面活性剂总浓度为0.5%、AOS与EAB复配比例为1:1、TA浓度为0.1%时,泡沫体系的综合指数可达107208 mL.min。该体系泡沫性能随温度升高而降低,但在70℃以下仍表现出良好的稳定性。黏弹性分析表明,当表面活性剂总浓度达到0.5%时,AOS与EAB分子相互缠绕形成大量蠕虫状胶束,显著提高体系的体相黏度和黏弹性。蠕虫状胶束结构的高黏弹性可有效延缓液膜排液速率,增强泡沫液膜强度,进而提高泡沫稳定性。

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    Gas channeling during CO2 flooding often reduces sweep efficiency and oil recovery. Foam injection has proven effective in controlling CO2 breakthrough. This study develops a wormlike micellar foam system using anionic surfactant AOS, zwitterionic surfactant EAB, and foam stabilizer alkylamine TA, systematically investigating its viscoelastic behavior. Experimental results show that when the total surfactant concentration reaches 0.5% with an AOS-EAB blend ratio of 1:1 and TA concentration of 0.1%, the foam system achieves a comprehensive index of 107,208 mL.min. While foam performance decreases with rising temperature, the system maintains good stability below 70°C. Viscoelastic analysis reveals that at 0.5% total surfactant concentration, AOS and EAB molecules intertwine to form abundant wormlike micelles, significantly enhancing the system"s bulk viscosity and viscoelasticity. The highly viscoelastic wormlike micellar structure effectively retards liquid film drainage and strengthens foam film stability, thereby improving overall foam performance.

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历史
  • 收稿日期: 2025-05-17
  • 最后修改日期: 2025-06-15
  • 录用日期: 2025-06-24
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