低渗透油藏用耐温耐盐量子点驱油剂
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中国石油股份公司重大专项“低渗/致密油藏大幅度提高采收率关键技术研究”课题四“低渗/致密油藏化学驱提高采收率关 键技术研究”(项目编号2023ZZ17YJ04)


Temperature- and Salt-Tolerant Quantum Dot-based Oil Displacing Agents for Low Permeability Oil Reservoirs
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    摘要:

    针对低渗透储层微纳米级孔喉发育,原油难以剥离启动,动用难度大的问题,通过蒸发溶剂热解法合成了C-Si 量子点驱油剂,采用透射电子显微镜(TEM)、傅里叶红外光谱分析仪(FT-IR)和X射线衍射仪(XRD)对合成的C-Si 量子点进行结构表征,考察了C-Si 量子点驱油剂的耐温耐盐性、界面活性、润湿性和驱油性能。研究结果表明,所合成的 C-Si 量子点为球形,粒径约 4 nm,分散性良好;XRD 识别出碳-硅量子点碳的(002)晶面和硅的(111)晶面,属于无定形状态;量子点表面含有羟基、羧基和氨基等官能团,这些基团可以与水分子形成氢键,提高了流体的稳定性。在温度为135 ℃的和矿化度为300 g/L 的条件下,荧光光谱未发生明显变化,具有良好耐温耐盐性能;在质量分数为0.3%时,C-Si 量子点可以降低油水界面张力至0.92 mN/m,且可以改变岩石表面润湿性为水湿。量子点驱油剂的渗吸效率高达47.4%,比模拟地层水大1倍以上,核磁T2谱识别到量子点可以波及到微小孔隙(1~10 ms)。在水驱(采收率为 63.95%)基础上,注入0.5 PV质量分数为0.3%的 C-Si 量子点驱油剂可提高采收率 22 百分点。所研发的碳-硅量子点驱油剂在低渗透油藏提高采收率方面显著,为油田高效开发提供了良好的借鉴。

    Abstract:

    In response to the problem of the development of micro-nano pore throats in low-permeability reservoirs,the difficulty in the stripping and activation of crude oil,and the difficulty in utilization,the carbon-silicon quantum dot oil displacement agent was synthesized by solvent evaporation and thermal decomposition method. The structure of the synthesized carbon-silicon quantum dots was characterized by transmission electron microscopy(TEM),Fourier transform infrared spectroscopy(FT-IR )and X-ray diffraction(XRD). The temperature resistance,salt tolerance,interfacial activity,wettability and oil displacement performance of the carbon-silicon quantum dot oil displacement agent were investigated. The results showed that the quantum dots were spherical with a particle size of about 4 nm and good dispersion. XRD identified the(002)crystal plane of carbon and the(111)crystal plane of silicon of carbon-silicon quantum dots,which were in an amorphous state. FT-IR indicated that the surface of the quantum dots contained hydroxyl,carboxyl and amino groups,which could form hydrogen bonds with water molecules,improving the stability of the fluid. Under the condition of temperature of 135 ℃ and salinity of 300 g/L,the fluorescence spectrum of the quantum dots did not change significantly,exhibiting good temperature and salt tolerance. When the mass fraction of the quantum dots was 0.3%, the carbon-silicon quantum dots could reduce the oil-water interfacial tension to 0.92 mN / m,and could change the wettability of the rock surface to water-wet. The imbibition efficiency of the quantum dot oil displacement agent was 47.4%,being twice as big as that of the simulated formation water. NMR T2 spectra identified that the quantum dots could reach the micro-pores(1—10 ms). On the basis of water flooding,oil recovery rate being of 63.95%,the injection of 0.5 PV carbon-silicon quantum dot oil displacement agent with mass fraction of 0.3% could enhance the recovery rate by 22 percentage points. The developed carbon-silicon quantum dot oil displacement agent is significant in enhancing oil recovery in low permeability reservoirs,which provides a good reference for efficient development of oil fields.

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陆小兵,闫若勤,杨立安,刘宇龙,万奇锋.低渗透油藏用耐温耐盐量子点驱油剂[J].油田化学,2025,42(4):679-684.
LU Xiaobing, YAN Ruoqin, YANG Li’an, LIU Yulong, WAN Qifeng. Temperature- and Salt-Tolerant Quantum Dot-based Oil Displacing Agents for Low Permeability Oil Reservoirs[J]. OILFIELD CHEMISTRY,2025,42(4):679-684.

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  • 在线发布日期: 2026-01-28
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