纳米复合超临界二氧化碳泡沫体系的研发及性能评价
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中国石油股份公司重大专项“低渗/致密油藏大幅度提高采收率关键技术研究”课题四“低渗/致密油藏化学驱提高采收率关 键技术研究”(项目编号 2023ZZ17YJ04)


Research and Performance Evaluation of Nano Composite Supercritical CO2 Foam Flooding System
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    摘要:

    针对CO2驱在微裂缝储层易发生气窜,波及效率低的问题,通过室内实验分别评价了阴离子、两性离子和非离子型CO2起泡剂和水溶性、气溶性纳米颗粒稳泡剂对泡沫性能的影响,优选纳米复合超临界CO2泡沫体系为0.3% 起泡剂CAB-35+0.5%水溶性纳米颗粒稳泡剂As30GA,并研究了储层条件下该纳米复合超临界CO2泡沫体系的泡沫性能,同时结合油藏环境,开展了纳米复合超临界CO2泡沫体系岩心驱油实验。结果表明,纳米复合超临界CO2泡沫体系的起泡体积达550 mL,析液半衰期为47 min,起泡、稳泡性能良好。纳米复合超临界CO2泡沫体系比普通泡沫(0.3% CAB-35)的黏弹模量增加约 90 mN/m,起泡剂和纳米颗粒协同大幅提高了泡沫强度和稳定性;纳米复合超临界CO2泡沫体系的耐温、耐压性能好,在油藏条件(矿化度10×104 mg/L、80 ℃、42 MPa)下,发泡体积达275 mL,析液半衰期达72 min。利用物理模型研究了纳米复合超临界CO2泡沫体系在多孔介质中的封堵及驱油性能,在0.5~2.0的气液比范围内,岩心驱替封堵压差最大为1.6 MPa,阻力因子大于50,采出程度比普通泡沫提高了28.8百分点。纳米复合超临界CO2泡沫体系的稳定性好,波及效率高,提高采收率能力优异,应用前景广阔。

    Abstract:

    Aiming at the problems of gas channeling and low sweep efficiency of CO2 flooding in micro-fractured reservoirs,the effects of anionic,zwitterionic and non-ionic CO2 foaming agents and water-soluble and gas-soluble nanoparticle foam stabilizers on foam performance were evaluated by laboratory experiments. The nano-composite supercritical CO2 foam system was optimized as 0.3% foaming agent CAB-35 + 0.5% water-soluble nanoparticle foam stabilizer As30 GA,and the foam performance of the nano-composite supercritical CO2 foam system under reservoir conditions was studied. At the same time,the core flooding experiment of the nano-composite supercritical CO2 foam system was carried out in the reservoir environment. The results showed that the foaming volume of the nano-composite supercritical CO2 foam system was 550 mL,the half-life was 47 min,indicating good foaming and foam stability performance. The viscoelastic modulus of nano-composite supercritical CO2 foam system was about 90 mN/m higher than that of ordinary foam(0.3% CAB-35). The foam strength and stability were greatly improved by the synergistic effect of foaming agent and nano-particles. The nano-composite supercritical CO2 foam system had good temperature resistance and pressure resistance. Under the reservoir conditions(salinity of 10×101 mg/L,80 ℃,42 MPa),the foaming volume reached up to 275 mL,and the half-life was 72 min. The plugging and oil displacement performance of nanocomposite supercritical CO2 foam system in porous media was studied by physical model. In the gas-liquid ratio of 0.5—2.0,the maximum plugging pressure difference of core displacement was 1.6 MPa,the resistance factor was greater than 50,and the recovery degree was 28.8 percentage points higher than that of ordinary foam. The nano-composite supercritical CO2 foam system had good stability,high sweep efficiency,excellent ability to improve oil recovery,and broad application prospects.

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易 萍,刘宇龙,陆小兵,于九政,杨立安,闫若勤,屈 肖.纳米复合超临界二氧化碳泡沫体系的研发及性能评价[J].油田化学,2025,42(4):656-663.
YI Ping, LIU Yulong, LU Xiaobing, YU Jiuzheng, YANG Li’an, YAN Ruoqin, QU Xiao. Research and Performance Evaluation of Nano Composite Supercritical CO2 Foam Flooding System[J]. OILFIELD CHEMISTRY,2025,42(4):656-663.

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