基于CMC@Fe3O4物理-化学双网络自修复水凝胶
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Dual Network Self-healing Hydrogel Based on CMC@Fe3O4
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    摘要:

    常规油田堵剂在油井深部堵水容易发生降解、失效,且堵剂吸液后体积膨胀,极易受到破坏而失去堵水效果,难以满足深部堵水需求。文章基于CMC@Fe3O4物理交联网络,以丙烯酰胺(AM)、2-丙烯酰胺基-2-甲基丙磺酸(AMPS)和 N-乙烯基吡咯烷酮(NVP)3种单体为共聚单体,过硫酸钾(KSP)为引发剂,对苯二酚(HQ)和六亚甲基四胺(HMTA)为交联剂,构建了物理-化学双网络自修复水凝胶P(AM/AMPS/NVP)/CMC@Fe3O4,并考察了该凝胶的凝胶强度、耐温耐盐性能和自修复性能。该双网络自修复凝胶体系的最优配方为:91.6% CMC@Fe3O4分散液,5.6% AM,2.4% AMPS,0.4% NVP,pH 值= 9,引发剂 KSP 为单体质量 0.8%,交联剂为 0.6% HQ 和 0.6%HMTA。该凝胶体系的凝胶强度为230.6 Pa,属于高强度凝胶。在高温(130 ℃)、高矿化度(2.2×105 mg/L)的地层条件下,30 d老化脱水率仅为6.21%,具有良好的耐温耐盐性。该凝胶体系对水相渗透率为 388 μm2 左右填砂管的封堵率在99%以上,突破压力在2.12 MPa以上,可以满足油田封堵需要。该凝胶在130 ℃老化1 h可实现自修复,凝胶断裂伸长率为 275%,修复效率达 100%。该双网络自修复水凝胶在凝胶强度、耐温耐盐性、封堵效果及自修复性能等方面均表现优异,满足油田深部堵水需求。

    Abstract:

    Conventional oilfield plugging agent in the deep water plugging of oil wells is prone to degradation and failure,the plugging agent is very easy to be damaged to lose the plugging effect after the absorption of liquid,it is difficult to meet the needs of deep water plugging. Based on the physical crosslinking network of CMC@Fe3O4,the physicochemical dual network self-healing hydrogel P(AM/AMPS/NVP)/CMC@Fe3O4 was constructed by using acrylamide(AM),2-acrylamido-2-methylpropanesulfonic acid(AMPS) and N-vinylpyrrolidone(NVP) as copolymerization monomers,potassium persulphate (KSP) as the initiator, hydroquinone(HQ)and hexamethylenetetramine(HMTA)as the crosslinking agent. The performance of gel strength,self-healing performance and temperature and salt resistance of the gel system were characterized. The optimum formulation of the self-healing gel system was as follows,91.6% CMC@Fe3O4 dispersion,5.6% AM,2.4% AMPS,0.4% NVP,pH= 9,the initiator KSP dosage was 0.8% by mass of the monomer,and the cross-linkers were 0.6% HQ and 0.6% HMTA. The gel strength of the gel was 230.6 Pa. The dehydration rate was only 6.21% after aging for 30 d at a high temperature of 130 ℃ and a high salinity of 2.2×105 mg/L, exhibiting good temperature and salt resistance. The plugging rate of the gel system to the sand-filled pipe with water phase permeability of about 388 μm2 was above 99%,and the breakthrough pressure was above 2.12 MPa,which could meet the needs of oilfield plugging. The self-healing of the gel could be achieved after aged at the temperature of 130 ℃ for 1 h,with a gel fracture elongation of 275% and a repair efficiency of 100%. the dual-network self-healing hydrogel demonstrates excellent performance in terms of gel strength,resistance to temperature and salt,sealing effectiveness and self-healing properties,and meets the requirements for deep plugging in oilfields.

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周香港,何 龙,黄雪莉,王 楠,吴 刚.基于CMC@Fe3O4物理-化学双网络自修复水凝胶[J].油田化学,2025,42(4):631-639.
ZHOU Xianggang, HE Long, HUANG Xueli, WANG Nan, WU Gang. Dual Network Self-healing Hydrogel Based on CMC@Fe3O4[J]. OILFIELD CHEMISTRY,2025,42(4):631-639.

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  • 在线发布日期: 2026-01-28
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