基于疏水缔合聚合物的中高黏滑溜水压裂液的减阻携砂和流变性能
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中国石油新疆油田分公司与西南石油大学合作项目“可逆超分子结构缔合聚合物压裂液体系评价技术”(项目编号 XJYT-2023-JS-6755)


Drag Reduction,Sand Carrying and Rheological Properties of Medium and High Viscosity Slick Water Fracturing Fluid Based on Hydrophobically Associating Polymer
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    摘要:

    针对传统滑溜水压裂液难以在中高黏度区间同时满足减阻与携砂性能的技术瓶颈,文章制备新型疏水缔合聚合物类压裂液,并在中高黏度区间测试其减阻携砂性能和流变性能,同时探究聚合物结构-流变-减阻携砂潜在关联机制。研究表明,当疏水缔合聚合物浓度超过临界缔合浓度(CAC)后,压裂液体系的减阻率增幅达 10%以上,支撑剂沉降速率降低 30%;通过增加疏水单体含量可实现携砂性能提升与减阻效率保持的协同优化。流变学数据表明关键流变参数的作用机制:悬砂性能与弹性模量(G')符合幂函数关系 v = aG'b ,减阻效率(DR)与第一法向应力差(N1)呈指数函数关系 DR = a + Ae[-0.5(N1-x/w)]。由疏水缔合聚合物构建高效减阻携砂体系,能够实现减阻和携砂的双重提升,建立的流变学调控模型为缔合聚合物压裂液的分子设计与性能优化提供了理论依据。

    Abstract:

    In view of the technical bottleneck that the traditional slickwater fracturing fluid is difficult to meet the drag reduction and sand carrying performance at the same time in the middle and high viscosity range,a new hydrophobically associating polymer fracturing fluid was prepared,and its drag reduction and sand carrying performance and rheological properties were tested in the middle and high viscosity range. At the same time,the potential correlation mechanism of polymer structure-rheology-drag reduction and sand carrying was explored. The results indicated that when the concentration of hydrophobically associating polymer exceeded the critical associating concentration(CAC),the drag reduction rate of the fracturing fluid system increased by more than 10%,and the proppant settling rate decreased by 30%. The synergistic optimization of enhanced proppant-carrying performance and maintained drag reduction efficiency could be achieved by increasing the content of hydrophobic monomers. Rheological data revealed the mechanism of key rheological parameters:the sand-suspending performance followed a power-law relationship with the elastic modulus(G')as v = aG'b,and the dag reduction efficiency exhibited an exponential relationship with the first normal stress difference(N1)as DR = a + Ae[-0.5(N1-x/w)]. Constructing a high-efficiency drag reduction and proppant-carrying system using hydrophobic associating polymers enabled dual improvements in drag reduction and proppant carrying. The established rheological regulation model provides a theoretical basis for the molecular design and performance optimization of associating polymer fracturing fluids.

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尹剑宇,邬国栋,陈小璐,郑博玄,张敬春,董景锋,金 诚.基于疏水缔合聚合物的中高黏滑溜水压裂液的减阻携砂和流变性能[J].油田化学,2025,42(4):594-606.
YIN Jianyu, WU Guodong, CHEN Xiaolu, ZHEN Boxuan, ZHANG Jingchun, DONG Jingfeng, JIN Cheng. Drag Reduction,Sand Carrying and Rheological Properties of Medium and High Viscosity Slick Water Fracturing Fluid Based on Hydrophobically Associating Polymer[J]. OILFIELD CHEMISTRY,2025,42(4):594-606.

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  • 在线发布日期: 2026-01-28
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