微胶囊乳液型聚合物驱油剂的性能
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国家自然科学基金项目“柔性胶囊聚合物驱提高采收率的基础理论研究”(项目编号 U21B2070)


Properties of Microencapsulated Emulsion Polymer Flooding Agent
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    摘要:

    聚合物驱是提高油田采收率成熟的重要技术,聚合物在配制、注入过程中由于受到配注工艺及炮眼高速剪切,聚合物溶液黏度损失严重,降低流度比、减小波及能力,影响采收率。为了解决聚合物抗剪切问题,研究了以聚氨酯为壳材的微胶囊乳液型聚合物的溶解、剪切、渗流、驱油性能。研究结果表明,微胶囊聚合物呈现胶囊微球的形貌,平均粒径在500 nm左右。微胶囊聚合物在水中持续搅拌过程中3 h开始出现破壳迹象,6 h后快速破壳,充分破壳时间约为 13 h。而在孔隙介质渗流过程中,微胶囊聚合物运移至 1.33 m(10.6 h)开始破壳,运移至 2 m(16 h)后才开始快速破壳,运移至3.33 m(26.6 h)后实现充分破壳释放聚合物,聚合物在水溶液中分子链相互聚集,呈较致密的网络结构,表现出明显的增黏特性。在均质与非均质岩心中微胶囊乳液聚合物采收率均高于HPAM采收率的6百分点以上。微胶囊乳液型聚合物经高速机械剪切后的黏度损失率仅为5%,在孔隙介质中能够建立较高的阻力系数与残余阻力系数,能够实现扩大波及体积提高采收率的效果。

    Abstract:

    Polymer flooding is a mature and important technology to enhance oil recovery. Due to the injection process and high-speed shear in the process of polymer preparation and injection,the viscosity loss of polymer is serious,the mobility ratio is reduced,the spread capacity is reduced,and the oil recovery is affected. In order to solve the problem of polymer shear resistance, the dissolution,shear,seepage and oil displacement properties of microencapsulated emulsion polymer with polyurethane as shell material were studied. The study showed that the microencapsulated polymer presented the morphology of capsule microspheres, and the average particle size of the microspheres was about 500 nm. The microencapsulated polymer began to show signs of shell breaking at 3 h,during the continuous stirring process in water,the shell was quickly broken after 6 h,and the full shell breaking time was about 13 h. In the process of seepage in porous media,when the microencapsulated polymer migrated to 1.33 m(10.6 h), the shell began to be broken;the shell rapidly was broken after migrated to 2 m(16 h),and the shell was fully broken after migrated 3.33 m(26.6 h),the shell was fully broken and the polymer was released. The molecular chains of the polymer aggregated with each other in the aqueous solution,showing a relatively dense network structure and obvious viscosity increasing characteristics. In homogeneous and heterogeneous cores,the oil recovery of microencapsulated emulsion polymer was higher than that of HPAM by more than 6 percentage points. The viscosity loss rate of the microencapsulated emulsion polymer after high-speed mechanical shear was only 5%,so high resistance coefficient and residual resistance coefficient could be established in the porous medium,which could realize the expansion sweep and enhancement of oil recovery.

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赵方剑,徐 辉,李德庆,宋 倩,董 雯,巩锦程.微胶囊乳液型聚合物驱油剂的性能[J].油田化学,2025,42(3):502-508.
ZHAO Fangjian, XU Hui, LI Deqing, SONG Qian, DONG Wen, GONG Jincheng. Properties of Microencapsulated Emulsion Polymer Flooding Agent[J]. OILFIELD CHEMISTRY,2025,42(3):502-508.

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  • 在线发布日期: 2025-11-04
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