海上油田用低初黏易降解堵水体系
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国家自然科学基金项目“热敏聚合物纳米流体高温触变机制研究”(项目编号52374028)


Water Plugging System with Low Initial Viscosity and Easy Degradation for offshore oilfield
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    摘要:

    为了解决常规聚合物凝胶在注入过程中存在注入压力大、注入困难的问题,文章制备了一种低初黏易降解凝胶体系,考察了该凝胶体系的注入性、成胶性能;并通过扫描电子显微镜(SEM)和万能力学压力机深入研究了该凝胶的微观形貌和机械强度;进一步地,采用热重分析及凝胶脱水率测试评价了该凝胶的耐温性和热稳定性;最后,通过可降解性实验和物理模拟实验评估了该凝胶的可降解性能和封堵性能。研究结果表明,适用疏松砂岩储层的低初黏易降解海水基凝胶体系配方为:0.2%聚合物VC-1+2%衣康酸+0.7%三聚氰胺+0.1%硫代硫酸钠,成胶温度范围为50~90 ℃,成胶时间在5~22 h调控,抗压强度(90 ℃)为310.4 kPa,表现出较高的机械强度。凝胶在90 ℃下熟化90 d的脱水率仅为7.4%,且最高耐温达到201.1 ℃,具有良好的长期稳定性和热稳定性。凝胶具有良好的封堵性和可降解性。物理模拟实验中凝胶的突破压力达到3.99 MPa,并在首次水驱突破后能进行二次运移封堵。当降解液QC-1与凝胶的质量比为1∶2时,在70 ℃下熟化10 d的降解率达到98.2%。采用研发的低初黏海水基堵水凝胶体系进行控水作业,典型井平均日产油量由2.3 t 增至62 t,含水率从99.7%降至72.4%,阶段增产原油量达到2710 t,可显著提升油井产量并降低含水率。

    Abstract:

    In order to solve the problems of high injection pressure and difficult injection in the injection process of conventional polymer gel,the hydrogel system with low initial viscosity and easy degradation was prepared,and the injection and gelation properties of the gel system were investigated. The microstructure and mechanical strength of the composites were studied by scanning electron microscopy(SEM)and universal mechanical testing machine. Furthermore,the heat resistance and thermal stability of the gel were evaluated by thermogravimetric analysis and gel dehydration rate test. Finally,the degradability and plugging performance of the gel were evaluated by degradability experiments and physical simulation experiments. The results showed that the formulation of seawater-based hydrogel system suitable for unconsolidated sandstone reservoirs with low initial viscosity and easy degradation was as follows,0.2 % polymer VC-1+2% itaconic acid+0.7% melamine+0.1% sodium thiosulfate, and the gelation temperature range of the gel system was 50— 90 ℃,the gelation time was regulated within 5—22 h,and the compressive strength(90 ℃)was 310.4 kPa,exhibiting high mechanical strength. The dehydration rate of the gel at 90 ℃ for 90 d was only 7.4%,and the maximum temperature resistance reached 201.1 ℃,showing good long-term stability and thermal stability. The gel had good plugging and degradability. In the physical simulation experiment,the breakthrough pressure of the gel reached 3.99 MPa,and after the first water flooding breakthrough,the secondary migration plugging could be carried out. When the mass ratio of the degradation solution QC-1 to the gel was 1∶2,the degradation rate of the gel reached 98.2% after aging for 10 days at the temperature of 70 ℃. When the water plugging operation was carried out by using the developed hydrogel system,the average daily oil production of typical wells increased from 2.3 t to 62 t,the water cut decreased from 99.7% to 72.4%,and the crude oil production increased by stages reached 2710 t,which could significantly increase oil well production and reduce water cut.

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兰夕堂,代磊阳,徐国瑞,郐婧文,冯 阳,徐 谦,薛明皓,陈立峰.海上油田用低初黏易降解堵水体系[J].油田化学,2025,42(3):427-433.
LAN Xitang, DAI Leiyang, XU Guorui, KUAI Jingwen, FENG Yang, XU Qian, XUE Minghao, CHEN lifeng. Water Plugging System with Low Initial Viscosity and Easy Degradation for offshore oilfield[J]. OILFIELD CHEMISTRY,2025,42(3):427-433.

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  • 在线发布日期: 2025-11-04
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