粉煤灰增效酚醛冻胶的流变性能
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Rheological Properties of Fly Ash Enhanced Phenolic Gel
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    摘要:

    利用冻胶堵水调剖是高含水油藏实现均衡驱替、提高采收率的重要技术,但在高温高盐油藏条件下冻胶的稳定性变差,且在生产压差下易被后续注入流体突破,导致冻胶封堵率低。向冻胶体系中添加微米级粉煤灰,以流变性能为表征指标,考察了粉煤灰填充的酚醛冻胶体系的注入性能、成胶时间、高温稳定性以及断裂应力等。研究结果表明,当粉煤灰用量为1%~2%时,冻胶成胶液的黏度为20.6~33.4 mPa·s,注入性能良好;成胶时间小幅度延缓,在90 ℃和150 ℃下成胶时间延长2~4 h;高温稳定性显著提高,150 ℃下稳定时间由20 d延长至120 d以上;冻胶的储能模量由7.4 Pa增至25.2~49.8 Pa,而断裂应力几乎不随粉煤灰用量而变化。添加粉煤灰能够有效提高冻胶热稳定性及封堵强度,在矿场试验中,粉煤灰增效冻胶表现出良好的堵水增油效果。

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    The use of gel plugging is an important technology for achieving balanced displacement and enhancing oil recovery in high water cut reservoirs. Under the conditions of high temperature and high salinity reservoir,the stability of the gel deteriorates, and it is easily broken through by subsequent injection fluids under production pressure differences,resulting in a low gel plugging rate. Therefore,it is necessary to propose effective ways to improve the performance of the gel. In the article,micrometer sized fly ash was added into the gel system,by the measurement of the rheological property of the gel system,the injection performance, gelation time,high-temperature stability,and fracture stress of phenolic gel system filled with fly ash was investigated. The results showed that when the amount of fly ash was 1%—2%,the viscosity of the gel forming solution was 20.6—33.4 mPa s,exhibiting good pumping performance. The gelation process was slightly delayed,with a 2—4 hour extension of gelation time at 90 ℃ and 150 ℃. The high-temperature stability of the gel system was significantly improved,and the stability time at 150 ℃ was extended from 20 days to more than 120 days. The storage modulus of the gel increased from 7.4 Pa to 25.2—49.8 Pa,while the fracture stress remained almost unchanged with the amount of fly ash used. The addition of fly ash could effectively improve the thermal stability and plugging strength of the gel. In field experiments,fly ash enhanced gel has shown good water control and oil incremental effect.

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何世伟,张 雯.粉煤灰增效酚醛冻胶的流变性能[J].油田化学,2025,42(3):419-426.
HE Shiwei, ZHANG Wen. Rheological Properties of Fly Ash Enhanced Phenolic Gel[J]. OILFIELD CHEMISTRY,2025,42(3):419-426.

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  • 在线发布日期: 2025-11-04
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