新型压裂液持续自生热增能驱油体系
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国家重点研发计划“稠油化学复合驱冷采工业示范应用”(项目编号 2018YFA0702405),山东省泰山产业创新项目“生物化学 复合提高难采稠油采收率技术创新及产业化”(项目编号tecx202312058


A Novel Sustained Self-heating Energy-enhancing Oil displacement Fracturing Fluid System
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    摘要:

    现有自生热体系通常在地面配制过程中便开始生热反应,所产生热量及气体在运移过程中流失从而无法高效作用于目的层。同时,针对低渗透储层,基于压裂液的高表面张力导致其在目标储层中波及系数低,影响压裂液多尺度造缝及原油驱动能力。针对上述生热压裂液性能缺陷,研制了新型压裂液持续自生热增能驱油体系。其中,基于碳酰胺与亚硝酸钠在盐酸溶液中的放热反应,通过分别加入游离态和油包水乳液态的盐酸溶液实现自生热体系的配制;以顺丁烯二酸酐、2-丙烯酰氨基-2-甲基丙磺酸、顺丁烯二酸二甲酯、甲基丙烯酸缩水甘油酯、丙烯酰胺和乙烯苯磺酸钠为单体,制得小分子聚合物增能驱油剂。研究了自生热体系的持续生热、产气能力,增能驱油剂的表/界面活性和对稠油的降黏能力,以及两者的配伍性和驱替原油效果。结果表明,自生热体系可于注入过程及注入 40 min 后两轮次放热产气,温度可达到 80 ℃以上,可同时实现热流体注入和储层加热,使原油降黏和储层增能。1500 mg/L 的增能驱油剂可使压裂液表面张力降低至 25 mN/m,压裂液与原油间的油水界面张力降低至0.0008 mN/m,室温下原油黏度从152.8 mPa·s降至38.2 mPa·s。自生热体系和驱油剂的配伍性良好,混合静置12 h后仍保持稳定,复配使用的采收率相较水驱可提高19.5百分点。

    Abstract:

    The existing self-heating system usually begins to generate heat during the ground preparation process,and then the heat and gas generated lost during transportation,making it difficult to efficiently act on the target layer. At the same time,for low-permeability reservoirs,the high surface tension of fracturing fluid leads to a low wave coupling coefficient in the target reservoir, which affects the multi-scale fracturing and crude oil driving capabilities of the fracturing fluid. Aiming at the performance defects of the thermal fracturing fluid mentioned above,a novel sustained self-heating energy-enhancing oil displacement fracturing fluid system was developed. Based on the exothermic reaction of carbamide and sodium nitrite in hydrochloric acid solution,the self-heating system was prepared by adding hydrochloric acid solution with free or water in oil emulsion liquid respectively. A small molecule polymer enhanced oil displacement agent was prepared using maleic anhydride,2-acrylamido-2-methylpropanesulfonic acid,dimethyl succinate, glycidyl methacrylate,acrylamide,and sodium ethylbenzenesulfonate as monomers. This article studied the sustained heat generation and gas production capacity of the heat generating system,the surface/interface activity and the viscosity reduction ability of the enhanced oil displacement agent,and the compatibility and oil displacement effect of the two. The results showed that the heat generating system could release heat and produce gas twice during the injection process and after 40 minutes of injection,with a temperature of over 80 ℃. It could simultaneously achieve the effects of hot fluid injection and reservoir heating,leading crude oil viscosity reduction and reservoir energy enhancement. When the dosage of enhanced oil displacement agent was 1500 mg/L,the surface tension of fracturing fluid could be reduced to 25 mN/m,the interfacial tension between fracturing fluid and crude oil could be reduced to 0.0008 mN/m,and then the viscosity of crude oil at room temperature could be reduced from 152.8 mPa·s to 38.2 mPa·s. The compatibility between heat generating system and oil displacement agent was good. The mixture remained stable even after 12 hours of static mixing. The recovery rate of compound use was significantly higher than that of water flooding by 19.5 percent points.

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樊家铖,束青林,翟 亮,刘海成,贾艳平,刘晓英,陶仕玉,孙成龙.新型压裂液持续自生热增能驱油体系[J].油田化学,2025,42(3):406-412.
FAN Jiacheng, SHU Qinglin, ZHAI Liang, LIU Haicheng, JIA Yanping, LIU Xiaoying, TAO Shiyu, SUN Chenglong. A Novel Sustained Self-heating Energy-enhancing Oil displacement Fracturing Fluid System[J]. OILFIELD CHEMISTRY,2025,42(3):406-412.

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  • 在线发布日期: 2025-11-04
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