压裂充填防砂用低温快速固化支撑剂
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中石化胜利油田博士后项目“水驱敏感稠油油藏防膨控砂体系研发”(项目编号 YKB2412),中石化胜利油田分公司项目“细 粉砂岩油藏深部控砂技术研究”(项目编号 YKC2314)


Proppant for Frac-pack Sand Control with Fast-curing Feature at Low Temperature
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    摘要:

    针对压裂充填防砂施工后期返排过程中支撑剂回流返吐问题,基于表面接枝改性手段制备了覆膜支撑剂,利用扫描电镜、能谱分析及红外光谱等手段表征了支撑剂覆膜层组成,通过对照实验考察了支撑剂与携砂液的配伍性及支撑剂回流控制性能,采用第一性原理计算的方法研究了支撑剂覆膜层分子间相互作用。研究结果表明,在砂比为5%~30%范围内,覆膜支撑剂与聚合物携砂液配伍性较好。分子间相互作用分析表明,支撑剂覆膜层中聚乙烯吡啶链段二聚体化在能量上是自发的。支撑剂可通过覆膜层中聚乙烯吡啶链段间的π-π相互作用,达到提升充填层稳定性的目的。导流能力测试结果表明,覆膜支撑剂显示出优异的低温快速固化性能,在50 ℃条件下养护2 h后即可将充填层导流能力提升 19.7%~53.1%,并将支撑剂临界回流速度提升1.6~3.0倍。在压裂防砂施工末期低井温、快速返排条件下保持充填层稳定性具有重要意义。

    Abstract:

    To solve the problem of proppant backflow during frac-pack completion,the coated proppant with fast-curing feature at low temperature was prepared by surface grafting modification and characterized by means of scanning electron microscopy,energy spectrum analysis and infrared spectroscopy. The compatibility of proppant and sand-carrying fluid as well as the flow back control performance was studied by contrast test. The interaction between the molecules of the proppant coatings was investigated by first-principles calculation. The results showed that the coated proppant presented favourable compatibility with the sand-carrying fluid with the sand proportion of 5%—30%. The dimerization of the poly(vinyl pyridine)molecules was energetically favorable and spontaneous. The results of intermolecular interaction calculation showed that the coated proppant could enhance the stability of the proppant pack through the π-π interaction between polyethylene pyridine chain segments. Conductivity tests showed that the coated proppant possessed excellent fast-curing performance at low temperature. After being cured at the temperature of 50 ℃ for 2 hours, the conductivity of the proppant pack could be increased by 19.7%—53.1% and the critical backflow velocity of proppant could be increased by 1.6—3.0 times. It is of great significance to maintain the stability of the proppant pack under the conditions of low well temperature and rapid backflow at the end stage of fracturing sand control constructions.

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李建达,唐 俊,贾培锋,任家敏,李贞文,王国强.压裂充填防砂用低温快速固化支撑剂[J].油田化学,2025,42(3):400-405.
LI Jianda, TANG Jun, JIA Peifeng, REN Jiamin, LI Zhenwen, WANG Guoqiang. Proppant for Frac-pack Sand Control with Fast-curing Feature at Low Temperature[J]. OILFIELD CHEMISTRY,2025,42(3):400-405.

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  • 在线发布日期: 2025-11-04
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