微胶囊聚合物在多孔介质中的动态调驱性能
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国家自然科学基金“柔性胶囊聚合物驱提高采收率的基础理论研究”(项目编号 U21B2070)


Dynamic Profile-control and Displacing Performance of Microcapsuled Polymer in Porous Media
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    摘要:

    微胶囊聚合物能够实现组分的缓慢释放增黏,避免配注过程中岩石孔喉剪切和水中还原性离子对聚合物溶液黏度影响。为明确微胶囊聚合物在多孔介质中的动态释放调驱性能和驱油适应性,在均质和非均质岩心中开展了破壳前、后微胶囊聚合物驱油实验,对不同驱替阶段剩余油分布进行CT扫描。研究结果表明,质量浓度为 1850 mg/L 的微胶囊聚合物破壳前初始黏度(0.7 mPa·s)较低,高温下随着时间的延长逐渐破壳,破壳 20 h后黏度显著升至 32.0 mPa·s。将微胶囊聚合物以破壳前和破壳后两种状态注入岩心驱油,开始注聚合物时(0~0.5 PV),破壳后体系的注入压力大于破壳前体系的;注聚合物后期(0.5~1.0 PV),破壳后体系的注入压力小于破壳前体系的。这说明以破壳前状态注入的微胶囊聚合物在多孔介质中确实能够发生动态破壳,引起注入压力的显著升高。破壳前体系驱油能力强于破壳后体系,均质和非均质岩心中采收率分别为43.5%、50.5%和39.0%、 44.5%。破壳前体系初始黏度低,能够更好地进入岩心深部释放驱油,岩心中后部残余油饱和度更低;而破壳后体系受运移能力以及剪切降解的影响主要驱替岩心前部原油,岩心中后部残余油饱和度更高,这也是破壳前体系提高采收率幅度高于破壳后体系的主要原因。

    Abstract:

    Microencapsulated polymers can achieve slow release and viscosity increase of components,avoiding the influence of rock pore throat shear and reducing ions in water on the viscosity of polyrmer solution during injection process. To clarify the dynamic release and oil displacement performance and adaptability of the microencapsulated polymer in porous media,the oil displacement experiments of microencapsulated polymer pre- and post- shell breaking were conducted in homogeneous and heterogeneous square rock cores,and CT scans were performed on the remaining oil distribution in different displacement stages to determine the oil displacement characteristics of the microencapsulated polymer. The results showed that the initial viscosity of the pre-shell breaking microencapsulated polymer system with mass concentration of 1850 mg/L was low at 0.7 mPa s,and gradually broke with time at high temperature. After shell breaking for 20 h,the viscosity significantly increased to 32.0 mPa·s. When injecting microencapsulated polymers system into the cores for oil recovery in pre- and post- shell breaking states,respectively,at the beginning of polymer injection(0—0.5 PV),the injection pressure of post-shell breaking polymer system was higher than that post-shell breaking;while in the late stage of injection(0.5—1.0 PV),the former was lower than the latter,It was indicated that the microencapsulated polymers injected in their pre-shell breaking state could indeed undergo dynamic shell breaking in porous media,causing a significant increase in injection pressure. The enhanced oil recovery of the pre-shell breaking system was stronger than that of the post-shell breaking system. The recovery rates in homogeneous and heterogeneous models were 43.5%,50.5%, 39.0%,44.5%,respectively. The initial viscosity of the pre- shell breaking polymer system was low,so the system could enter the deep part of the model to release and drive oil,as a result,the residual oil saturation in the rear part of the model was lower;however,after the shell was broken,the system was mainly displaced by the migration capacity and shear degradation of the crude oil in the front part of the model,resulting in higher residual oil saturation in the middle and rear parts,which was also the main reason why the oil recovery rate of pre- shell breaking system rate was more than that of the post- shell breaking system.

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徐 辉,高 源,董 雯,王业飞,宋 倩,巩锦程,丁名臣.微胶囊聚合物在多孔介质中的动态调驱性能[J].油田化学,2025,42(2):349-355.
XU Hui, GAO Yuan, DONG Wen, WANG Yefei, SONG Qian, GONG Jincheng, DING Mingchen. Dynamic Profile-control and Displacing Performance of Microcapsuled Polymer in Porous Media[J]. OILFIELD CHEMISTRY,2025,42(2):349-355.

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  • 在线发布日期: 2025-07-25
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