大港油田沧东孔二段页岩油与水的乳化特性及影响因素
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中国石油重大科技专项“陆相页岩油规模增储与勘探开发技术研究”(项目编号 2023ZZ15),中国石油大港油田公司博士后 科研项目“沧东孔二段泥纹型页岩油提产用功能表活剂研究”(项目编号2023BO059)


Emulsification Characteristics and Influencing Factors of Shale Oil and Water in the Second Member Kongdian Formation of Cangdong Sag in Dagang Oilfield
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    摘要:

    大港油田沧东凹陷孔二段页岩油藏一次压裂开采初期见效明显,但后期能量和产量下降较快,而且采出液乳化严重,导致页岩油采收率降低,集输阻力变大,开发难度增加。通过分析大港油田沧东凹陷孔二段页岩油的物理化学性质、页岩油与水的乳化特性及其影响因素,揭示页岩油与水的乳化原因和乳化机制,提出改善页岩油乳化增黏的方法。研究结果表明,孔二段页岩油的平均蜡含量高于 20%,凝固点高于 35 ℃,页岩油重质烃含量越高越利于乳化现象的发生。页岩油中的胶质、沥青质等含氮极性组分,以及蜡晶的存在,导致页岩油与水在流动过程中形成油包水(W/O)乳状液,产生乳化增黏现象。随着含水量的增加,页岩油黏度呈先增加后降低的趋势,含水量在 50%~70%时乳化后页岩油黏度达到最大值,是脱水原油黏度的3.23~7.45 倍。升高乳化温度、增加水相矿化度以及侵入压裂液组分,均会使页岩油与水乳化形成的W/O乳状液稳定性增强。当乳化页岩油再乳化时会形成O/W/O 多重乳状液,黏度进一步升高;但当再乳化时添加少量乳化剂可使乳化页岩油从W/O型反相为O/W型,从而降低页岩油黏度,提高其流动性。在开展页岩油注水增能时需考虑页岩油的物理化学性质,同时研发高活性页岩油增产用表面活性剂将是后续工艺设计和产品研发的重点。

    Abstract:

    The shale oil reservoir in the second member of Kongdian formation(Ek2)of Cangdong Sag in Dagang oilfield exhibits significant effects during the initial stage after primary fracturing,but the energy and production decline rapidly in later stages. Furthermore,the produced fluids are severely emulsified,resulting in a reduction of shale oil recovery,and increase of pipeline transportation resistance and development challenges. Through systematic analysis of the physicochemical properties of Ek2 shale oil,emulsification characteristics of shale oil-water and their influencing factors,this study revealed the reasons and mechanisms of shale oil-water emulsification,and proposed methods to mitigate emulsification-induced viscosity enhancement. The results showed that the Ek2 shale oil contained over 20% wax content on average with a pour point exceeding 35 ℃. Moreover,the high content of heavy hydrocarbons favored the occurrence of emulsification phenomenon. Nitrogen-containing polar components(e.g.,resins and asphaltenes)and wax crystals facilitated the formation of water-in-oil(W/O)emulsions during the flow of shale oil and water, resulting in emulsification-induced viscosity enhancement phenomenon. The viscosity of shale oil increased first and then decreased with increasing water content,peaking at 50%—70% water content with viscosity values 3.23—7.45 times that of dehydrated crude oil. The stability of W/O emulsions formed during shale oil-water emulsification process was enhanced by increasing emulsification temperature,water phase salinity,and intruding fracturing fluid composition. Additionally,complex O/W/O multiple emulsions generated when the emulsified shale oil was re-emulsified,further increasing the viscosity of system. However,introducing a small amount of emulsifier during the re-emulsifying process enabled phase inversion from W/O to oil-in-water(O/W)emulsion,thus effectively reducing the viscosity of shale oil and improving fluidity. Consequently, it was necessary to consider the physicochemical properties of shale oil as conducting water injections and energy enhancement for shale oil reservoirs. The development of high-activity surfactants for shale oil stimulation would be a focus for subsequent process design and product research.

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李 崎,王晓燕,葛红江,李东平,王海峰,张 楠.大港油田沧东孔二段页岩油与水的乳化特性及影响因素[J].油田化学,2025,42(2):340-348.
LI Qi, WANG Xiaoyan, GE Hongjiang, LI Dongping, WANG Haifeng, ZHANG Nan. Emulsification Characteristics and Influencing Factors of Shale Oil and Water in the Second Member Kongdian Formation of Cangdong Sag in Dagang Oilfield[J]. OILFIELD CHEMISTRY,2025,42(2):340-348.

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  • 在线发布日期: 2025-07-25
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