用于海上油田的包覆型缓释调剖体系
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中国海洋石油集团有限公司海洋油气高效开发全国重点实验室 2024 年自主前瞻基础项目“缓释包裹凝胶智能靶向调驱体系 运移规律量化研究”(项目编号 CCL2024TJT0NST1180),中海油十四五重大科技项目“海上高含水油田提高注采效率关键采油工艺技术”(项目编号 KJGG2021-0502)


Coated Slow-release Profile Control System for Offshore Oilfields
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    摘要:

    海上油田调剖技术是高含水油藏的一种有效治理手段,聚合物凝胶封堵强度大但注入性较差,聚合物微球注入性能好但封堵强度受浓度影响较大。针对以上问题,采用反相乳液聚合法,以单体AM、AA聚合反应物为聚合物微球的内核层,可分解交联剂PEGDA与功能单体AM、AA包覆聚合形成聚合物微球的外壳层,再将有机交联剂SZ修饰在高分子外壳层,得到包覆型缓释调剖体系。研究了体系增黏性能影响因素,结合显微镜、透射电镜、核磁共振波谱和傅里叶红外测试手段对增黏组分释放过程进行了系统表征,并开展岩心物模实验考察调剖体系在目标区块的注入性能与封堵性能。研究结果表明,该调剖体系初始以微米级微球状态存在,在1~7 d溶胀、释放增黏组分,增黏释放过程受单体、交联剂加量及温度、矿化度、剪切速率等环境因素影响,其中丙烯酸加量为40%时体系黏度最优,通过调节交联剂PEGDA加量(0.005%~0.300%)可实现增黏组分的可控释放,高活性交联剂SZ加量为2%兼具最优成胶时间与黏度特性。该体系在目标区块高渗储层的阻力系数<5,注入端、中部、深部的残余阻力系数分别达18、8、5,具有良好的注入能力及深部封堵能力。

    Abstract:

    Profile control technology in offshore oil fields is an effective treatment method for reservoirs with high water cut. Polymer gel has a high plugging strength but poor injectivity,while polymer microsphere has a good injection performance,but its plugging strength is greatly affected by concentration. To overcome the above problems,the AM/AA polymers were used as the core layer of the polymer microspheres,and the decomposable crosslinking agent PEGDA and the functional monomers AM and AA were coated to form the shell layer of the polymer microspheres,and then the organic crosslinking agent SZ was modified in the polymer shell layer to obtain a coated sustained-release profile control system using the inverse emulsion polymerization method. The factors affecting the viscosity increasing performance of the system was investigated,and its release process of viscosity components was also systematically characterized by using microscopy,transmission electron microscopy,nuclear magnetic resonance spectroscopy and Fourier transform infrared testing methods. Besides,core flooding experiments were conducted to characterize its injection performance and sealing performance in the target block. The results indicated that the system initially existed in a micrometer sized spherical state,and it swelled and released viscosity increasing components within 1—7 d. The process of releasing viscosity increasing components was influenced by several factors such as the amount of monomer and crosslinking agent,temperature,mineralization degree and shear rate. When the acrylic acid amount was 40%,the system viscosity was optimal. By adjusting the amount of crosslinking agent PEGDA(0.005%—0.300%),controllable release of the viscosity-increasing component could be achieved,2% highly active crosslinker SZ demonstrated both optimal gelation time and viscosity characteristics. The resistance coefficient of the system in the target high-permeability reservoir was <5,and the residual resistance coefficients at the injection end,middle,deep part reached 18,8,5,respectively,indicating good injection capacity and deep plugging capability.

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李彦阅,吕金龙,庞长廷,鲍文博,李晓骁,徐国瑞,王浩颐,李宜强.用于海上油田的包覆型缓释调剖体系[J].油田化学,2025,42(2):260-268.
LI Yanyue, LYU Jinlong, PANG Changting, BAO Wenbo, LI Xiaoxiao, XU Guorui, WANG Haoyi, LI Yiqiang. Coated Slow-release Profile Control System for Offshore Oilfields[J]. OILFIELD CHEMISTRY,2025,42(2):260-268.

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  • 在线发布日期: 2025-07-25
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