适用于非常规油气储层的超分子表面活性剂压裂液
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中国石油集团科技重大专项“稠油绿色低碳开发技术与试验”(项目编号2023ZZ23-06)


Supramolecular Surfactant Fracturing Fluid Suitable for Unconventional Oil and Gas Reservoirs
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    摘要:

    为了提高非常规油气储层的压裂开发效率,以长链脂肪酸酰氯、N,N-二甲基丙二胺和氯乙烯为原料,制得超分子表面活性剂CPA-1;将2% CPA-1与3%氯化钾混合,制得超分子表面活性剂压裂液。通过红外光谱和核磁共振氢谱表征了CPA-1的结构,比较了CPA-1溶液和压裂液的微观形貌,评价了压裂液的耐温抗剪切性、耐盐性、携砂能力、破胶性和储层保护性能。结果表明,CPA-1溶液含有较多的蠕虫状胶束,氯化钾的加入可以通过静电屏蔽作用和氢键作用进一步促进蠕虫状胶束的生长,使其形成复杂的胶束聚集体结构。压裂液的耐温抗剪切性能较好,在120 ℃、170 s-1 下剪切120 min 的黏度可达51.8 mPa·s。压裂液的耐盐性能较强,使用矿化度为25 350、101 400、202 800 mg/L 的盐水配制压裂液对其剪切黏度的影响较小,剪切120 min 后的黏度为53.1~62.4 mPa·s。此外,该压裂液还具有良好的携砂能力、破胶性能和储层保护性能。90 ℃时陶粒在压裂液中的沉降速度仅为0.091 cm/min。煤油体积分数为20%时,可使压裂液在80 ℃下实现30 min 内快速破胶,破胶液无残渣,并且具有较低的表面张力(26.2 mN/m)和油水界面张力(0.84 mN/m)。压裂液破胶液对渗透率为 1.08×10-3 ~32.07×10-3 μm2的人造岩心和天然岩心的基质渗透率损害率为3.50%~8.70%,对储层的伤害较小,适用于非常规油气储层压裂施工。

    Abstract:

    In order to improve the fracturing development efficiency of unconventional oil and gas reservoirs,a supramolecular surfactant CPA-1 was prepared using long-chain fatty acid chlorides,N,N-dimethylpropanediamine and vinyl chloride as raw materials. Supramolecular surfactant fracturing fluid was prepared by mixing 2% CPA-1 and 3% potassium chloride. The structure of CPA-1 was characterized by infrared spectroscopy and nuclear magnetic resonance hydrogen spectroscopy,and then the microstructure of CPA-1 solution and fracturing fluid was compared. The temperature and shear resistance,salt tolerance,sand carrying capacity,gel breaking ability,and reservoir protection performance of fracturing fluid were evaluated. The results showed that CPA-1 solution contained a significant amount of worm like micelles. The addition of potassium chloride could further promote the growth of worm like micelles through electrostatic shielding and hydrogen bonding,leading to the formation of complex micelle aggregate structures. The temperature resistance and shear resistance of fracturing fluid were good. The viscosity could reach 51.8 mPa s after shearing for 120 minutes at 120 ℃ and 170 s-1. The salt tolerance of fracturing fluid was strong. The use of salt water with mineralization degrees of 25 350,101 400 and 202 800 mg/L to prepare fracturing fluid had little effect on its shear viscosity. The viscosity after shearing 120 minutes was 53.1—62.4 mPa·s. In addition,the fracturing fluid also had good sand carrying capacity,gel breaking performance and reservoir protection performance. At 90 ℃,the settling velocity of ceramic particles in fracturing fluid was only 0.091 cm/min. When the volume fraction of kerosene was 20%,the fracturing fluid could achieve rapid gel breaking within 30 minutes at 80 ℃,with no residue,low surface tension(26.2 mN/m)and oil-water interfacial tension(0.84 mN/m). The matrix permeability damage rate of artificial and natural rock cores with a permeability of 1.08×10-3—32.07×10-3 μm2 by fracturing and gel breaking liquid was 3.50%—8.70%,which caused less damage to the reservoir and was suitable for fracturing construction in unconventional oil and gas reservoir.

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蔡喜东,张 娜,葛方嵘.适用于非常规油气储层的超分子表面活性剂压裂液[J].油田化学,2025,42(2):236-243.
CAI Xidong, ZHANG Na, GE Fangrong. Supramolecular Surfactant Fracturing Fluid Suitable for Unconventional Oil and Gas Reservoirs[J]. OILFIELD CHEMISTRY,2025,42(2):236-243.

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  • 在线发布日期: 2025-07-25
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