具有双重交联结构的低成本高性能降滤失剂
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中海油田服务股份有限公司前瞻基础类项目“高AM含量降滤失剂合成方法与性能关系研究”(项目编号E-23246003)


Low Cost and High-performance Filtrate Reducer with Dual Cross-linking Structure
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    摘要:

    人工合成聚合物作为水基钻井液降滤失剂仅通过改变共聚物官能团的类型和比例已很难满足钻井工程的需要,尤其是在超高温高盐度条件下通过加大功能单体的用量会增加其成本。通过调整交联剂,在主单体丙烯酰胺(AM)中添加抗盐单体2-丙烯酰胺-2-甲基丙磺酸(AMPS)和耐温单体N-乙烯基吡咯烷酮(NVP),同时采用极少量的有机交联剂N,N'-亚甲基双丙烯酰胺(MBA)和金属交联剂柠檬酸锆(MC),制备具有双重交联结构的降滤失剂。以聚合物的高温降滤失效果为考察指标,采用单因素实验优化合成条件,并利用激光粒度分析仪、傅里叶变换红外光谱、扫描电子显微镜和热重分析仪分析了共聚物的粒径分布、微观结构、表面形貌、耐热性能和抗温机理等。结果表明,降滤失剂的最佳制备条件为:AM、AMPS、NVP单体质量比为18∶1∶1,MBA与MC的质量比为1∶3,引发剂用量为1.0%,搅拌速度400 r/min,反应温度65 ℃。具有双重交联结构降滤失剂的平均粒径为16.48 μm,耐温高达350 ℃。含有5000 mg/L 降滤失剂的基浆在210 ℃下热滚16 h后的高温高压滤失量和API滤失量分别由77.6、18.8 mL降至31.4、6.8 mL。具有双重交联结构降滤失剂的抗高温机理为:水解后的聚合物分子链与金属交联剂进行二次交联,保护了水解的聚合物分子链不会快速降解,从而形成更加致密复杂的三维网络结构,使得聚合物降滤失剂表现出优异的耐温抗盐降滤失性能。

    Abstract:

    When artificially synthesized polymers are used as filtrate reducers for water-based drilling fluids,it is difficult to meet the needs of drilling engineering by simply changing the type and proportion of copolymer functional groups. Increasing the usage of energetic monomers will undoubtedly increase the cost,especially under ultra-high temperature and high salinity conditions. This study prepared a filtrate reducer with dual cross-linking structure by adding salt resistant monomer 2-acrylamide-2-methylpropanesulfonic acid (AMPS) and temperature resistant monomer N-vinylpyrrolidone (NVP) to the main monomer acrylamide(AM),simultaneously using a very small amount of organic cross-linking agent N,N'-methylenebisacrylamide(MBA) and metal cross-linking agent zirconium citrate(MC). Using the high-temperature filtration reduction effect of polymers as the evaluation index,single factor experiments were used to optimize the synthesis conditions. The particle size distribution, microstructure,surface morphology,heat resistance,and temperature resistance mechanism of copolymers were analyzed using laser particle size analyzer,Fourier transform infrared spectroscopy,scanning electron microscope,and thermogravimetric analyzer. The results showed that the optimum preparation conditions for the filtrate reducer were obtained as follows:18∶1∶1 the mass ratio of AM,AMPS and NVP monomers,1∶3 the mass ratio of MBA and MC,1.0% initiator dosage,400 r/min stirring speed,and 65 ℃ reaction temperature. The average particle size of filtrate reducer with dual cross-linking structure was 16.48 μm. Its temperature resistance could reach to 350 ℃. The high temperature and high pressure filtration loss and API filtration loss of the system containing 5000 mg/L polymer decreased from 77.6 mL and 18.8 mL to 31.4 mL and 6.8 mL respectively after 16 hours of hot rolling at 210 ℃. The high-temperature resistance mechanism of the filtrate reducer with dual cross-linking structure was that the hydrolyzed polymer molecular chains underwent secondary crosslinking with metal cross-linking agent,protecting the hydrolyzed polymer molecular chains from rapid degradation and forming a more dense and complex three-dimensional network structure,resulting in excellent temperature and salt resistance filtration reduction performance.

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王志永,周新宇,李怀科,耿 铁.具有双重交联结构的低成本高性能降滤失剂[J].油田化学,2025,42(2):198-205.
WANG Zhiyong, ZHOU Xinyu, LI Huaike, GENG Tie. Low Cost and High-performance Filtrate Reducer with Dual Cross-linking Structure[J]. OILFIELD CHEMISTRY,2025,42(2):198-205.

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  • 在线发布日期: 2025-07-25
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