页岩油钻井用环保型耐温抗盐增黏剂
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中国石油集团油田技术服务有限公司科技重大专项“钻完井复杂防治技术研究”(项目编号2023T-001-002)


Environmentally Friendly Viscosity Enhancer with Temperature Resistance and Salt Tolerance for Shale Oil Drilling
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    摘要:

    为了提高水基钻井液用增黏剂的耐温抗盐性能以及环保性能,满足页岩油钻井施工的需求,以甲基丙烯酰胺(MAA)、N-乙烯基吡咯烷酮(NVP)和可聚合季铵盐阳离子单体(H-12)为原料,制备了环保型耐温抗盐增黏剂HBZ-2。通过红外光谱和核磁共振氢谱表征了增黏剂 HBZ-2的分子结构,分析了其作用机理,并考察了其增黏性能、耐温抗盐性能、环保性能以及钻井液的基本性能。结果表明,在相同的实验条件下,HBZ-2的增黏性能、耐温性能和抗盐性能均优于同类型的增黏剂HE300 和 80A51。当增黏剂 HBZ-2的加量为1%时,可使海水基浆的表观黏度由 10.5 mPa·s 增至 54.5 mPa·s;经过 200 ℃高温老化,含 20%氯化钠或5%氯化钙海水基浆的黏度仍能达到30 mPa·s以上,耐温抗盐性能较强。加入1%增黏剂HBZ-2的钻井液体系经过高温老化后的各项基本性能均较为稳定,页岩滚动回收率大于 90%,耐温可达 200 ℃。增黏剂 HBZ-2和钻井液体系具有较低的生物毒性和良好的生物可降解性,EC50值分别为 204 400、120 500 mg/L,BOD5/COD 值分别为 40.9%、33.6%。另外,增黏剂HBZ-2不含重金属,而钻井液体系中的部分重金属含量也远低于相关行业标准,环保性能优良。耐温抗盐增黏剂HBZ-2的性能优良,适用于对环保性能要求较高的海上页岩油钻井。

    Abstract:

    In order to improve the temperature resistance and salt tolerance as well as environmental performance of water-based drilling fluid viscosity enhancer,and meet the needs of shale oil drilling construction,viscosity enhancer HBZ-2 was prepared using methacrylamide (MAA),N-vinyl pyrrolidone (NVP) and polymerizable quaternary ammonium salt cationic monomer (H-12)as raw materials. The molecular structure of HBZ-2 was characterized by infrared spectroscopy and nuclear magnetic resonance hydrogen spectroscopy,and then its mechanism of action was analyzed. The thickening performance,temperature resistance,salt tolerance and environmental performance of HBZ-2,and the basic properties of drilling fluid were investigated. The results showed that under the same experimental conditions,the thickening performance,temperature resistance and salt tolerance of HBZ-2 were superior to those of the same type of viscosity enhancer HE300 and 80A51. When the dosage of HBZ-2 was 1%,the apparent viscosity of seawater based slurry could be increased from 10.5 mPa·s to 54.5 mPa·s. After high-temperature aging at 200 ℃,the viscosity of seawater based slurry containing 20% sodium chloride or 5% calcium chloride could still reach over 30 mPa·s,indicating strong temperature resistance and salt tolerance. The basic properties of drilling fluid system containing 1%HBZ-2 after high-temperature aging were relatively stable,with a shale rolling recovery rate of over 90% and a temperature resistance of up to 200 ℃. HBZ-2 and drilling fluid system had low biological toxicity and good biodegradability,with EC50 value of 204 400 mg/L and 120 500 mg/L,respectively,and BOD5/COD value of 40.9% and 33.6%,respectively. In addition,HBZ-2 did not contain heavy metals,while the content of some heavy metals in drilling fluid system was also much lower than that of the relevant industry standards, indicating excellent environmental performance. The viscosity enhancer HBZ-2 had excellent performance and was suitable for offshore shale oil drilling with high environmental performance requirements.

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马海云,吕 双,颜 寒,丁柯宇.页岩油钻井用环保型耐温抗盐增黏剂[J].油田化学,2025,42(2):191-197.
MA Haiyun, LYU Shuang, YAN Han, DING Keyu. Environmentally Friendly Viscosity Enhancer with Temperature Resistance and Salt Tolerance for Shale Oil Drilling[J]. OILFIELD CHEMISTRY,2025,42(2):191-197.

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  • 在线发布日期: 2025-07-25
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