纳米纤维素增强的高机械强度聚丙烯酰胺复合水凝胶
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国家科技重大专项“低渗-致密油藏高效提高采收率新技术”(项目编号2017ZX05009-004)


Polyacrylamide Composite Hydrogel with High Mechanical Strength Reinforced by Nanocrystalline Cellulose
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    摘要:

    为了增强聚丙烯酰胺凝胶的强度,利用纳米纤维素制备丙烯酰胺/纳米纤维素复合水凝胶,通过质构仪和 流变仪研究了纳米纤维素对复合水凝胶拉伸性能、压缩性能、黏附性能及黏弹特性的影响,并利用扫描电镜观察 了复合水凝胶的微观结构。结果表明,添加纳米纤维素的复合水凝胶的拉伸强度、压缩应力、黏附力、弹性模量 及黏性模量均明显大于不含纳米纤维素的聚丙烯酰胺凝胶。当丙烯酰胺与纳米纤维素的质量比为5∶3 时,形成 的复合水凝胶的拉伸强度、压缩应力及弹性模量均达到最大。复合水凝胶的韧性增强效果明显,拉伸应力及黏 附力较聚丙烯酰胺凝胶提高近3 倍。与聚丙烯酰胺凝胶相比,复合水凝胶的网络结构更加致密,机械强度和与井 筒管壁的黏附效果更好,可用于油气田的欠平衡钻井。

    Abstract:

    In order to enhance the strength of polyacrylamide(PAM)gel,nanocrystalline cellulose(NCC)was used to prepare AM/NCC composite hydrogel. The effects of NCC on the tensile property,compressive property,adhesion property and viscoelastic property of composite hydrogel were investigated by using texture analyzer and rheometer,and then the microstructure of composite hydrogel was observed by scanning electron microscope (SEM). The results showed that the tensile strength, compressive stress,adhesive force,elasticity modulus and viscosity modulus of composite hydrogel were significantly higher than those without NCC. When the mass ratio of AM to NCC was 5∶3,the tensile strength,compressive stress and elasticity modulus of composite hydrogel reached the maximum. The toughness of composite hydrogel was significantly enhanced. Meanwhile,the tensile stress and adhesion force were nearly 3 times higher than those of PAM gel. Compared with PAM gel,the network structure of PAM/NCC composite hydrogel became denser. Furthermore,the mechanical strength and adhesion to wellbore wall became better. PAM/NCC composite hydrogel could be used for underbalanced drilling in oil and gas fields.

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马彦琪,林梅钦,董朝霞,张储桥.纳米纤维素增强的高机械强度聚丙烯酰胺复合水凝胶[J].油田化学,2023,40(4):608-613.
MAYanqi, LIN Meiqin, DONG Zhaoxia, ZHANG Chuqiao. Polyacrylamide Composite Hydrogel with High Mechanical Strength Reinforced by Nanocrystalline Cellulose[J]. OILFIELD CHEMISTRY,2023,40(4):608-613.

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  • 在线发布日期: 2024-01-10
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