Foam fracturing is a common technical mean in the fracturing and stimulation of coalbed methane reservoir. The selection of foaming agent is particularly important. In order to develop a foaming agent with better foam performance,lower cost and excellent comprehensive performance,the foaming agent(HBS-J)was prepared from tea saponin,alkenyl succinic anhydride and sodium bisulfite by esterification and sulfonation. The structure of HBS-J was characterized by infrared spectrum,and then the foaming property,salt and oil resistance,surface activity,and reservoir protection of HBS-J were evaluated. The results showed that HBS-J had good foaming performance,salt and oil resistance,and surface activity. When the mass fraction of HBS-J was 0.3%,the foaming volume was 590 mL,the half-life of foam was 2562 s,and then the composite index of foam could reach 25 193 mL min,indicating strong foaming ability and foam stability. When the mass concentrations of Na+,Ca2+ and Mg2+ in brine solution were 79 310,5405 and 2021 mg/L respectively or the volume fraction of kerosene reached 25%,HBS-J could still form a relatively stable foam system. Furthermore,its foaming ability and salt and oil resistance were significantly better than those of traditional foaming agents,such as sodium dodecyl sulfate,sodium α-olefin sulfonate,coconut amidopropyl betaine. When the mass fraction of HBS-J was 0.25%—0.35%,the surface tension of solution(about 40 mN/m)was relatively low. The reservoir protection performance of HBS-J was good. The damage rate to the permeability of coalbed matrix was less than 10%. It would not cause serious damage to the coalbed methane reservoir during foam fracturing construction. HBS-J met the requirements of coalbed methane reservoir foam fracturing construction on the comprehensive performance of foaming agent.
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XI Baohua, LIU Dongna. Foaming Agent for Foam Fracturing of Coalbed Methane Reservoir with Tea Saponin as Raw Material[J]. OILFIELD CHEMISTRY,2024,41(4):610-615.