Effect of Autogenous Heat Generation System on Gel Breaking Performance of Fracturing Fluid
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    Abstract:

    Aiming at the problems of incomplete gel breaking and low flowback rate of fracturing fluid after fracturing in shallow low-temperature oil and gas well,the optimum reaction parameters of three autogenous heat generation systems,including nitrite and ammonium salt,chromium trioxide and glucose,and hydrogen peroxide were selected. Under the reaction parameters,the heat generation of three systems and their influence on gel breaking performance of fracturing fluid were analyzed. The results showed that the best reaction parameter for nitrate and ammonium salt system was obtained as follows:2 mol/L activator HCl,8 mol/L heat generating agent NaNO2 and NH4Cl(molar ratio 1∶1). That for chromium trioxide and glucose system was obtained as follows:1mol/L activator HCl,14% heat generating agent CrO3 and C6H12O6(mass ratio 1∶1). That for hydrogen peroxide system was obtained as follows:0.3% activator MnO2,30% heat generating agent H2O2. Hydrogen peroxide system had the highest heat generation,and the temperature could reach 91 ℃. In the gel breaking experiment of fracturing fluid,the adding sequence of glucose and chromium trioxide system and gel breaker ammonium persulfate had no influence on gel breaking effect of fracturing fluid. The hydrogen peroxide system should be added with gel breaker at the same time. However,for the nitrite and ammonium salt system,the gel breaker was added after the heat generation system. The nitrite and ammonium salt system was the best additive for gel breaking system of fracturing fluid and had the best gel breaking performance,which could reduce the viscosity of fracturing fluid to less than 6 mPa·s.

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SHEN Xiulun, JIANG Guancheng, LI Xinliang, ZHEN Yanzhong, CUI Kaixiao, LI Wuquan. Effect of Autogenous Heat Generation System on Gel Breaking Performance of Fracturing Fluid[J]. OILFIELD CHEMISTRY,2021,38(4):620-626.

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  • Online: January 29,2022
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