A hydrophobically associating polymer flooding agent with high temperature resistance,salt resistance and good solubility in weak alkaline environment was exploited. A alkali-soluble hydrophobically associating terpolymer P(AM/AA/BEM) was synthesized by 2-(2-[4-(1,1,3,3-tetramethylbutyl)phenoxy]ethoxy)ethanol(OP-10)as emulsifier,acrylamide(AM),acrylic acid(AA)and behenyl polyoxyethylene ether methacrylate(BEM)as raw materials. The synthesis condition of P(AM/AA/BEM)was optimized and the performance of polymer solution was studied in detail. The results showed that the optimum reaction condition of P(AM/AA/BEM)was obtained as follows:20% total monomer mass fraction,25% AA mole fraction,0.2% BEM mole fraction, 0.3% initiator 2,2'-azobis[2-methylpropionamidine] dihydrochloride (V50) mass fraction, 45℃ reaction temperature and 8 hrs reaction time. It showed good thickening property,heat resistance(90℃),salt tolerance(20 g/L)and shear thinning. There was strong synergistic effect between P(AM/AA/BEM)and sodium dodecylbenzenesulfonate(SDBS). When 400 mg/L SDBS was added in 1 g/L P(AM/AA/BEM),the viscosity of hybrid system increased 3.3 times. P(AM/AA/BEM)showed better thickening property,heat and shearing resistance and salt tolerance than partially hydrolyzed polyacrylamide(HPAM).
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FENG Rusen, XUE Songsong, CHEN Junhua, GUO Yongjun, PU Di. Synthesis and Solution Properties of Alkali-soluble Hydrophobically Associating Terpolymer P(AM/AA/BEM)[J]. OILFIELD CHEMISTRY,2017,34(1):165-170.