原油组分对乳状液稳定性及破乳机理影响
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1.中国石油天然气集团有限公司超深层复杂油气藏勘探开发技术研发中心;2.四川省成都市新都区西南石油大学

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Effect of Crude Oil Components on Emulsion Stability and Demulsification Mechanism
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西南石油大学

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    摘要:

    在解决某联合站原油低温破乳脱水问题之前,首先研究了原油组分影响乳状液的稳定性,通过将原油组分进行分离制备成模拟油后分别研究各组分界面性质、Zeta电位、粒径分布以及微观形貌,结果表明石蜡基型原油乳状液稳定性影响大小为:石蜡>胶质>芳香分>饱和分。然后研究原油乳状液在破乳剂PR-1作用下的界面性质以及粒径分布与微观形貌的变化,分析发现原油乳状液的破乳脱水主要经历了乳化水滴的絮凝、聚结、沉降过程。破乳剂首先会溶解进入到油相中,然后通过分子运动扩散到油水界面进行吸附,顶替置换掉原油本身的天然活性组分从而进行重排形成新的强度更低的界面膜,导致界面膜破裂释放原来被包裹的乳化水滴,最终实现联合站低温破乳脱水。

    Abstract:

    To solve the problem of low-temperature demulsification and dehydration of crude oil at a target joint station, the influence of crude oil components on emulsion stability was first investigated.Crude oil components were separated to prepare model oils, and the interfacial properties, zeta potential, particle size distribution and microstructure of the corresponding emulsions were systematically characterized.The results show that the effects of different components on the stability of water-in-oil (W/O) emulsions follow the order: paraffin wax > resins > aromatics > saturates.Subsequently, the changes in interfacial properties, particle size distribution and microstructure of the crude oil emulsion under the action of demulsifier PR-1 were investigated.Mechanism analysis reveals that the demulsification and dehydration process of the crude oil emulsion mainly undergoes three stages: flocculation, coalescence and sedimentation of emulsified water droplets.The demulsifier first dissolves in the oil phase, then diffuses to the oil-water interface and adsorbs there via molecular motion. It displaces the native active components in crude oil and rearranges to form a new interfacial film with lower strength.This leads to the rupture of the interfacial film and the release of the encapsulated emulsified water droplets, ultimately achieving low-temperature demulsification and dehydration for the target joint station.

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  • 收稿日期:2026-05-29
  • 最后修改日期:2026-07-08
  • 录用日期:2026-07-16
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