耐温耐盐聚合物冻胶体系构建及长效稳定性研究
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1.中国石油大学华东石油工程学院;2.中海石油中国有限公司深圳分公司;3.海洋油气高效开发全国重点实验室

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TE39

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国家自然科学基金面上项目:海上疏松砂岩油藏深部颗粒动态自堆积与储层就地修复机制研究,项目编号5257044231


Research on the Gelling Mechanism and Long-Term Stability of Temperature-Resistant and Salt-Tolerant Polymer Gels
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School of Petroleum Engineering,China University of Petroleum East China,Qingdao

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    摘要:

    针对高温高盐油藏环境下常规聚合物冻胶成胶稳定性差、有效期短的技术瓶颈,基于聚合物冻胶在偏碱性环境中稳定性更强、pH<5的酸性环境抑制成胶的特性,优选碱性络合剂LH-2与稳定剂WD-1复配,构建强化型冻胶网络结构。通过成胶性能评价、长期稳定性测试、热重分析及岩芯封堵实验,系统研究了该体系的成胶规律与应用性能。实验结果表明:在矿化度45550 mg/L(二价离子质量浓度2000 mg/L)、温度140℃条件下,当聚合物与交联剂质量分数均提升至0.6%时,冻胶经180天老化后脱水率仅为2.8%,冻胶强度维持在D~E级;该体系在90~140℃温度区间内均能快速成胶(成胶时间17~24h),对渗透率500×10?³μm²的岩芯封堵率高达99.9%,注入压力峰值仅0.19MPa,兼具优异的注入性与封堵效果。研制的耐高温长效冻胶体系为深部高温高盐油藏调剖技术提供了关键数据支撑与新型技术方案。

    Abstract:

    To address the technical challenges of poor gelation stability and short service life of conventional polymer gels in the high-temperature and high-salinity (HTHS) environments of deep reservoirs, a reinforced polymer gel system was fabricated by compounding the alkaline complexing agent LH-2 and stabilizer WD-1, leveraging the inherent property that polymer gels exhibit superior stability in alkaline media while gelation is inhibited under acidic conditions (pH<5). The gelation regularity and application performance of the developed system were systematically investigated through gelation property evaluation, long-term stability testing, Thermal Gravimetric Analyzer (TGA), and core plugging experiments. Experimental results demonstrate that under the conditions of 45550 mg/L salinity (2000 mg/L divalent ion concentration) and 140 ℃, when the mass fractions of both polymer and cross-linking agent are increased to 0.6%, the gel exhibits a dehydration rate of merely 2.8% after 180 days of aging, with the gel strength maintained at grade D~E. Within the temperature range of 90~140 ℃, the system achieves rapid gelation with a gelation time of 17~24 h. For cores with a permeability of 500×10?³μm², the plugging rate reaches as high as 99.9% and the maximum injection pressure is only 0.19MPa, indicating excellent inject ability and plugging efficiency. This high-temperature resistant and long-term stable gel system provides critical data support and a novel technical approach for the profile control technology in deep HTHS reservoirs.

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  • 收稿日期:2026-04-17
  • 最后修改日期:2026-07-09
  • 录用日期:2026-07-16
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