纳米ZrO<sub>2</sub>增强疏水缔合聚合物压裂液体系在230℃高温致密气藏中的应用*
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1.海洋油气高效开发全国重点实验室;2.油气钻采工程湖北省重点实验室;3.低碳催化与二氧化碳利用全国重点实验室

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TE357.2

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国家重点实验室开放基金“自生热复合增效体系在多孔介质中的增产机理及热量扩散模拟 ”,编号202521149286


Optimization and Application of a Nano-ZrO? Enhanced Instant-Soluble Polymer Fracturing Fluid System for 230°C High-Temperature Tight Gas Reservoirs
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state Key Laboratory of low carbon catalysis and carbon dioxide utilization

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    摘要:

    针对WC特低渗致密砂岩高温高压气藏(井口泵压高达79 MPa,闭合压力86 MPa,温度230 ℃)面临的施工压力高、加砂困难、裂缝延伸难度大、常规压裂液耐温不足及淡水资源受限等挑战,本研究研发了一套耐230 ℃高温的纳米增强速溶疏水缔合型磺化聚合物压裂液体系,优化配方为:0.5% SRP-1 +0.02% 亲水纳米ZrO?+0.6%YCJ-1+0.2%pH调节剂+1%KCl+0.5% ZP-1。该体系采用纳滤海水配制,在230 ℃、170 s?1下剪切2 h后黏度保持172 mPa.s,破胶彻底(黏度3.23 mPa.s),岩心伤害率<19%。创新提出了小-中-大粒径组合支撑工艺(40/70目:30/50目: 20/40目=1:2:1),在86 MPa闭合压力下导流能力达15 D.cm,有效保障了裂缝长期导流能力并降低了加砂难度。现场应用表明,该工艺成功解决了高温高压致密砂岩储层的压裂难题,加砂量与改造效果显著提升,为类似海上高温气藏的高效开发提供了可靠技术支撑。

    Abstract:

    Addressing the challenges in fracturing the WC ultra-low permeability, tight sandstone, high-temperature, and high-pressure gas reservoir (wellhead pressure: 79 MPa; closure pressure: 86 MPa; temperature: 230°C), such as high treating pressure, proppant placement difficulty, fracture extension complexity, inadequate temperature resistance of conventional fluids, and limited freshwater availability, this study developed a seawater-based, nano-enhanced fracturing fluid stable at 230°C. The optimized formulation (0.5% SRP-1 + 0.02% hydrophilic nano-ZrO? + 0.6% YCJ-1+0.2% pH buffer+ 1% KCl + 0.5% ZP-1) maintained a viscosity of 172 mPa.s after shearing at 230°C and 170 s?1 for 2 h, broke completely to 3.23 mPa.s, and caused less than 19% core damage. A composite proppant placement strategy using a blend of small, medium, and large mesh sizes (40/70: 30/50: 20/40 = 1:2:1), which achieved a fracture conductivity of 15 D.cm under 86 MPa closure pressure, ensuring long-term flow capacity while mitigating placement difficulties. Field applications confirmed that this integrated approach successfully addressed the technical challenges, significantly increasing proppant placement efficiency and stimulation performance, providing robust technical support for the efficient development of similar offshore high-temperature gas resources.

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  • 收稿日期:2026-03-18
  • 最后修改日期:2026-05-28
  • 录用日期:2026-06-24
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