低渗储层纳米二氧化硅辅助无碱二元体系驱油效果影响因素研究
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1.东北石油大学 石油工程学院 提高油气采收率教育部重点实验室;2.东北石油大学;3.大庆永铸石油技术开发有限公司

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页岩油储层CO2响应型纳米渗吸排驱流体防膨及原油动用机理 编号:LH2024E007


Factors Influencing the Oil Displacement Efficiency of Alkali-Free Binary System Assisted by Nano-SiO2 in Low-Permeability Reservoirs
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Northeast Petroleum University

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    摘要:

    针对长庆某区块油田低渗油藏储层物性,构建阴离子表活剂重烷基苯磺酸盐(HABS)、两性离子表活剂椰油酰胺丙基羟磺基甜菜碱(CAPH)与纳米SiO2的无碱复合体系〔CHS-x,x为纳米SiO2添加量〕。采用FTIR、粒径分析、SEM手段对CHS-x 进行表征,测定了CHS-x体系的界面张力、润湿性变化、乳化性能评价、储层吸附变化量。实验表明CHS-0.15%体系在温度45℃、地层水矿化度11000 mg·L-1下静置60天时,界面张力仍可达10-3 数量级,30天时析水率降至仅为26%,同时使油湿性岩心片向弱水湿性转变(接触角105.2°至61.2°),纳米SiO2能显著提升抗吸附性效果。模拟驱油实验结果表明,注入0.7 PV 0.15%(w)纳米SiO2+0.3% (w)表面活性剂(m(HABS):m(CAPH)=7:3)组成的CHS-0.15%体系,能在纳米SiO2注入前提高采收率28.63% ,级差2、5下均不同程度上提高采收率,这为解决类似长庆某区块油田低温低渗油藏技术开发上的难题提供了针对性的技术参考。

    Abstract:

    An alkali-free composite system, denoted as CHS-x (where x represents the nano-SiO? concentration), was constructed comprising anionic heavy alkyl benzene sulfonate (HABS), zwitterionic cocamidopropyl hydroxysulfobetaine (CAPH), and nano-SiO?, tailored for the low-permeability reservoir characteristics of a specific block in the Changqing Oilfield. The CHS-x systems were characterized via FTIR, particle size analysis, and SEM, followed by evaluations of interfacial tension (IFT), wettability alteration, emulsification performance, and adsorption behavior on reservoir rocks. Experimental results demonstrated that the CHS-0.15% formulation maintained an IFT in the order of 10?3 mN/m after 60 days of static aging at 45°C and a formation water salinity of 11,000 mg/L, exhibited a water separation rate of only 26% after 30 days, and effectively altered oil-wet core slices to weakly water-wet conditions (reducing the contact angle from 105.2° to 61.2°), with nano-SiO? significantly enhancing resistance to adsorption losses. Core flooding simulations indicated that injecting 0.7 PV of the CHS-0.15% system (composed of 0.15 wt% nano-SiO? and 0.3 wt% surfactants with an HABS:CAPH mass ratio of 7:3) increased oil recovery by 28.63% compared to water flooding, showing enhanced recovery across permeability contrasts of 2 and 5; these findings provide targeted technical insights for addressing development challenges in low-temperature, low-permeability reservoirs analogous to those in the Changqing Oilfield.

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  • 收稿日期: 2026-03-09
  • 最后修改日期: 2026-04-08
  • 录用日期: 2026-04-21
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