新型耐高温纤维接枝可膨胀树脂的合成与性能评价
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1.中海油田服务股份有限公司;2.中国石油大学华东石油工程学院;3.中联煤层气有限责任公司

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“超深长裸眼固井低密度水泥浆技术研究”(编号:YHB25YF006)、“复杂地层钻井液”(编号:52322401)、“超深特深层油气钻采流动调控”(编号:52288101)。


Synthesis and performance evaluation of novel temperature-resistant fiber grafted swellable resin
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East China Petroleum Engineering College, China University of Petroleum

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    摘要:

    针对现有聚丙烯酸类可膨胀树脂在高温条件下易水解、膨胀速率过快、承压能力不足等问题,提出一种新型耐高温纤维接枝可膨胀树脂的制备方法。通过在聚合物主链中引入耐高温五元杂环结构,并接枝改性聚乙烯短纤维进行增强,显著提升了树脂的综合性能。通过对接枝率、膨胀倍数、保水量及单体转化率等关键参数的优化,系统确定了纤维改性与树脂聚合的最佳反应条件。热重分析、高温老化实验与耐盐性测试结果表明,该改性树脂在180 ℃高温及一定矿化度的盐水中仍能保持稳定的膨胀性能。在多种复杂环境中,树脂的最大膨胀时间稳定在60 min,且在最大膨胀倍数下,凝胶的压缩模量提升达363%。该纤维接枝可膨胀树脂表现出优异的延时膨胀性、高温稳定性和高承压强度,在高温缝洞堵漏、深层高渗透层调剖等油田开发领域具有广阔的应用前景。

    Abstract:

    To address the issues of easy hydrolysis, excessively rapid expansion rate, and inadequate load-bearing capacity in existing polyacrylic-based expandable resins under high-temperature conditions, this study proposes a novel method for preparing a high-temperature-resistant fiber-grafted expandable resin. By incorporating a high-temperature-resistant five-membered heterocyclic structure into the polymer backbone and reinforcing it with grafted modified polyethylene short fibers, the overall performance of the resin was significantly enhanced. Through systematic optimization of key parameters, including the grafting rate, expansion ratio, water retention capacity, and monomer conversion rate, the optimal reaction conditions for fiber modification and resin polymerization were determined. Thermogravimetric analysis, high-temperature aging experiments, and salt resistance tests demonstrated that the modified resin maintains stable expansion performance under high-temperature conditions of 180°C and in saline solutions with certain mineralization levels. In various complex environments, the maximum expansion time of the resin remained stable at 60 minutes, and the compressive modulus of the gel increased by up to 363% at the maximum expansion ratio. The fiber-grafted expandable resin exhibited excellent delayed expansion properties, high-temperature stability, and superior load-bearing strength, indicating broad application potential in oilfield development areas such as high-temperature fracture and vug plugging and deep high-permeability layer profile control.

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  • 收稿日期:2026-02-05
  • 最后修改日期:2026-07-02
  • 录用日期:2026-07-16
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