固井用纳米材料及纳米复合材料研究进展
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1.中国石油集团工程技术研究院有限公司;2.中国石油集团西部钻探工程有限公司准东钻井公司

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TE256.6 DOI

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国家自然基金基础科学中心项目“超深特深层油气钻采流动调控”(编号:52288101)和中国石油重点课题《超深特深层油气钻完井井筒工作液流动调控研究》(编号:2023DQ0529)


Research progress on nanomaterials and nanocomposites for well cementing
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    摘要:

    纳米材料技术发展迅速,已成为油气井固井工程领域研究和应用的热点。本文论述了固井领域常用的无机纳米材料、有机纳米颗粒、聚合物/无机纳米复合材料的研究和应用进展,其中纳米硅、纳米沸石粉、埃洛石纳米管、纳米碳酸钙、纳米黏土、纳米氧化镁、纳米氧化铝、碳纳米管/碳纳米纤维、石墨烯等功能材料在油井水泥石力学性能改进方面效果显著,但由于纳米材料难分散问题而限制了其规模应用;聚合物胶乳、纳米乳液等有机纳米颗粒,可明显改善水泥浆防窜性能、前置液洗油效果和冲洗效率等,对保障固井施工安全和固井质量发挥了重要作用;聚合物纳米复合材料改性技术在聚合物类固井外加剂耐温能力提升和综合性能改善等方面研究较为深入,其综合性能较传统聚合物大大提高,甚至取得重大技术突破。本文针对复杂深层及非常规油气井固井重大工程技术难点,提出了聚合物纳米复合材料类固井外加剂研发建议,并从纳米表面接枝改性、纳米插层复合技术2方面提出了产品研发路线,对抗超高温高性能固井关键外加剂研发具有重要的指导作用,有望推动复杂油气井固井工程技术进步。

    Abstract:

    The nanomaterial technology with rapid development has become a hot research and application topic in the field of oil and gas well cementing engineering. This article discusses the research and application progress of commonly used nanomaterials and polymer nanocomposites in the field of well cementing. Among them, nanoscale functional materials including silicon dioxide, zeolite powder, halloysite nanotubes, calcium carbonate, clay, magnesium oxide, alumina, carbon nanotubes/carbon nanofibers and grapheme have significant effects on improving the mechanical properties of set cement. However, their application is limited due to the difficulty of dispersing nanomaterials. Polymer latex, nanoemulsion and other organic nanoparticles can significantly improve the channeling prevention performance of cement slurry, the oil washing effect and flushing efficiency of preflush, and play an important role in ensuring the safety and quality of cementing. The modification technology of polymer nanocomposites has been extensively studied in terms of improving the temperature resistance and comprehensive performance of polymer cementing additives. Its comprehensive performance has been greatly improved compared to traditional polymers, and even significant technological breakthroughs have been made. The article proposes suggestions for the research and development of polymer nanocomposite used as cementing admixtures in response to major technical difficulties in complex deep and unconventional oil and gas well cementing. It also proposes product research and development routes from two aspects: nano surface grafting modification and nano intercalation technology, which have an important guiding role in the research and development of key cementing additives. It is expected to promote the progress of complex oil and gas well cementing engineering technology.

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  • 收稿日期: 2023-11-14
  • 最后修改日期: 2024-01-28
  • 录用日期: 2024-02-26
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