一种两亲型驱油聚合物的合成与性能研究
DOI:
作者:
作者单位:

中海油能源发展工程技术分公司

作者简介:

通讯作者:

中图分类号:

基金项目:

*中海油能源发展科研项目“油水响应聚合物产品研发与应用”资助,项目编号:HFKJ-ZX-GJ-2022-03-02


Prerparation and properties of an amphiphilic oil displacement polymer
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    海上油田三次采油技术面临着严苛的油藏条件,如高温、高盐、油稠等,同时平台空间十分有限。这种特殊的作业环境要求驱油聚合物必须具有很强的耐温抗盐、长期热稳定性以及快速溶解的能力,因此,开发出同时具有良好增粘和速溶性能的驱油聚合物已经迫在眉睫。基于以上目的,开发了一种两亲型驱油聚合物(HAP),通过丙烯酰胺(AM)、丙烯酸(AA)、2-丙烯酰胺-2-甲基丙磺酸(AMPS)以及自主研发的长链烷基聚醚类两亲功能单体(POM),采用自由基水溶液聚合低温引发方式制备了新型两亲驱油聚合物HAP,通过合成工艺优化获得性能良好的聚合物产品。与市售耐温抗盐聚丙烯酰胺相比,在模拟油藏条件下,HAP溶液表现出突出的耐温抗盐、抗剪切性能以及良好的长期稳定性。岩心驱替实验表明,模拟SZ36-1油田条件HAP聚合物目标液的原油采收率比相同浓度的市售耐温抗盐聚丙烯酰胺高8.8个百分点。

    Abstract:

    The tertiary oil recovery technology in offshore oil fields faces severe reservoir conditions, such as high temperature, high salinity, and oil viscosity, while the platform space is very limited. This special working environment requires oil displacement polymers to have strong salt resistance, temperature resistance, long-term thermal stability, and rapid dissolution ability. Therefore, it is urgent to develop oil displacement polymers with good viscosity increasing and instant solubility performance. Based on the above objectives, an amphiphilic oil displacement polymer (HAP) was developed. A new type of HAP was prepared by using acrylamide (AM), acrylic acid(AA),2-acrylamide-2-methylpropanesulfonic acid (AMPS), and independently developed long-chain alkyl polyether based amphiphilic functional monomers (POM). The free radical aqueous solution polymerization was used for low-temperature initiation to prepare the HAP, and a high-performance polymer product was obtained through optimization of the synthesis process. Compared with commercially available temperature and salt resistant polyacrylamide, HAP solution exhibits outstanding temperature and salt resistance, shear resistance, and good long-term stability under simulated reservoir conditions. The core displacement experiment shows that the crude oil recovery rate of HAP polymer target fluid under simulated SZ36-1 oilfield conditions is 8.8 percentage points higher than that of commercially available temperature and salt resistant polyacrylamide with the same concentration.

    参考文献
    相似文献
    引证文献
引用本文
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期: 2023-11-09
  • 最后修改日期: 2023-12-13
  • 录用日期: 2023-12-22
  • 在线发布日期:
  • 出版日期:
点击这里给我发消息

点击这里给我发消息