煤层气储层泡沫压裂用新型起泡剂的研制及性能评价
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1.山西工程职业学院;2.太原理工大学,矿业工程学院

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TE254;TE377 ? ?????????????????? ???

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国家自然科学基金面上项目(201901D111050)


Development and performance evaluation of new foaming agent for foam fracturing of coalbed methane reservoir
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    摘要:

    泡沫压裂是煤层气储层压裂增产改造中常用的一种技术手段,起泡剂的选择尤为重要。为了研究出泡沫性能更好、成本更低以及综合性能优良的起泡剂,以茶皂苷、烯基琥珀酸酐和亚硫酸氢钠为原料,通过酯化和磺化反应,制备了一种新型起泡剂HBS-J,通过红外光谱对其结构进行了表征,并对其综合性能进行了评价。结果表明:新型起泡剂HBS-J的起泡性能、耐盐耐油性能和表面活性均比较好,当HBS-J的质量分数为0.3%时,泡沫综合指数可以达到25193mL·min,发泡能力和泡沫稳定性均比较强;当盐水溶液中Na+浓度为79310mg/L、Ca2+浓度为5405mg/L、Mg2+浓度为2021mg/L或者煤油体积分数达到25%时,HBS-J仍能形成比较稳定的泡沫体系,并且其起泡能力和耐盐耐油能力均明显优于传统的起泡剂。HBS-J还具有良好的储层保护性能,对煤层基质渗透率的伤害率小于10%,在泡沫压裂施工过程中不会对煤层气储层造成严重的伤害。研究结果认为新型起泡剂HBS-J能够作为煤层气储层泡沫压裂用起泡剂使用。

    Abstract:

    Foam fracturing is a common technical means in the fracturing and stimulation of coalbed methane reservoir, and the selection of foaming agent is particularly important. In order to develop a foaming agent with better foam performance, lower cost and excellent comprehensive performance, a new foaming agent HBS-J was prepared from tea saponin, alkenyl succinic anhydride and sodium bisulfite through esterification and sulfonation reaction. Its structure was characterized by infrared spectrum, and its comprehensive performance was evaluated. The results show that the new foaming agent HBS-J has good foaming performance, salt resistance, oil resistance and surface activity. When the mass fraction of HBS-J is 0.3%, the comprehensive index of foam can reach 25193 mL · min, and the foaming ability and stability of foam are relatively strong; When the Na+ concentration in the saline solution is 79310mg/L, the Ca2+ concentration is 5405mg/L, the Mg2+ concentration is 2021mg/L or kerosene volume fraction reaches 25%, HBS-J can still form a relatively stable foam system, and its foaming ability, salt resistance and oil resistance are significantly better than traditional foaming agents. HBS-J also has good reservoir protection performance, and the damage rate to the permeability of coal bed matrix is less than 10%, so it will not cause serious damage to the coalbed methane reservoir during the foam fracturing construction. The research results show that the new foaming agent HBS-J can be used as a foaming agent for foam fracturing of coalbed methane reservoir.

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  • 收稿日期: 2023-10-24
  • 最后修改日期: 2023-11-29
  • 录用日期: 2023-12-22
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