一种纳米均相缓速酸体系的开发与应用
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1.中海油田服务股份有限公司;2.中国石油大学(北京)非常规油气科学技术研究院

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国家自然科学基金"纳米乳液在致密砂岩储层中的吸附特性及其解水锁机制研究"(52004306);国家科技重大专项“中亚和中东地区复杂碳酸盐岩油气藏采油采气关键技术研究与应用”(2017ZX05030005)


Development and Application of a Nano Homogeneous Phase Retarded Acid System
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    摘要:

    针对碳酸盐岩储层改造乳化酸高摩阻、稠化酸聚合物残渣伤害问题,开发了一种新型缓速酸体系—纳米均相缓速酸,该体系由20%HCL、5% PA-NA纳米乳液、0.1%减阻剂及功能型添加剂组成。采用旋转岩盘仪、扫描电镜、?EDS能谱仪、电导率仪、粒度分析仪、界面张力仪、润湿角测定仪、摩阻仪、酸蚀裂缝导流仪、岩心流动仪等实验仪器对纳米均相缓速酸体系的性能进行了系统分析评价。实验结果表明,纳米均相缓速酸体系是一种内相为油、外相为酸的纳米均相分散体系,粒径分布为8~100nm;其克服了乳化酸高摩阻、稠化酸聚合物残渣伤害的缺点,具备强缓速(缓速率大于90%)、低摩阻(降阻率大于75%)、低粘、低伤害和高酸蚀裂缝导流性能;可同时溶有机垢和无机垢(沥青溶解率大于5%,碳酸盐岩溶解率100%);可解除储层乳化、水锁、润湿改性伤害。纳米均相缓速酸体系通过带负电纳米乳液吸附在带正电灰岩表面,建立酸岩“隔离屏障”,实现强缓速;通过差异化酸蚀及粘性指进,实现高酸蚀裂缝导流;通过纳米乳液特殊油水互溶结构,实现有机垢和无机垢同时解除。该体系在现场成功应用,对碳酸盐岩储层储层深部改造及多重伤害解除具有重要意义。

    Abstract:

    A new retarded acid system, nano homogeneous phase retarded acid was developed to solve the problems of high friction of emulsified acid and damage of gelled acid polymer residue in carbonate reservoir. The system consists of 20%HCL, 5% PA-NA nano emulsion, 0.1% drag reducer and functional additives. The properties of homogeneous phase retarded acid system were systematically analyzed and evaluated by means of rotating rock disc instrument, scanning electron microscope, EDS spectrometer, conductivity meter, particle size analyzer, interfacial tensiometer, wetting Angle tester, friction tester, acid erosion crack conductivity meter and core flow meter. The experimental results show that the homogeneous phase retarded acid system is a nano homogeneous dispersion system with oil in the inner phase and acid in the outer phase, and the particle size distribution is 8~100nm. It overcomes the disadvantages of high friction of emulsified acid and damage of thickened acid polymer residue, and has the properties of strong retarded speed (retarded rate greater than 90%), low friction resistance (lower resistance rate greater than 75%), low viscosity, low damage and high acid corrosion fracture conductivity. It can dissolve organic scale and inorganic scale at the same time (asphalt dissolution rate is greater than 5%, carbonate karst hydrolysis rate is 100%); It can remove the damage of reservoir emulsification, water lock and wetting modification. The homogeneous phase retarded acid system is adsorbed on the surface of positive electric limestone by negatively charged nano-emulsion to establish the "isolation barrier" of acid rock and achieve strong slow speed. Through differentiated acid erosion and viscous fingering, high acid erosion fracture diversion is realized. Through the special oil-water miscible structure of nano-emulsion, the organic scale and inorganic scale can be removed simultaneously. The successful application of this system in the field is of great significance for deep reservoir stimulation and multiple damage removal of carbonate reservoir.

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  • 收稿日期: 2023-10-06
  • 最后修改日期: 2024-01-21
  • 录用日期: 2024-02-06
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