压裂用微乳增产助剂的研制与性能评价
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1.低渗透油气田勘探开发国家工程实验室;2.长庆油田分公司石油预探项目部;3.长庆油田分公司天然气勘探项目部

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中国石油股份公司重大专项项目“储层改造关键技术与装备研究”(编号:2021DJ4506)


Research and performance evaluation of the microemulsion additives used in fracturing stimulation
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    摘要:

    针对低渗致密油藏的渗吸增产,基于“压-注-采”一体化施工方式,从提高压裂液性能出发,以阴离子表面活性剂SY-1和9-葵烯酸甲酯MS-9为主要原料,通过拟三元相图研究相行为,采用正交试验优化配方研制出增产助剂微乳液ME,并通过室内实验评价了其性能,测试了在压裂过程中的增产效果。结果表明,该微乳液的平均粒径为70.5nm;能够在长时间静置(180天)和高速离心(8000rpm)条件下保持稳定;可将界面张力降低至10-4~10-3mN/m数量级;将接触角降低约45°;经岩心粉8次吸附后仍能够维持高界面活性,抗吸附能力较强;与压裂液配伍性良好,以未添加微乳液ME的压裂液作为空白对照,在模拟压裂入井阶段时可将洗油效率提升57~64%,焖井阶段可将渗吸置换效果提升16%,返排阶段可将原油采出率增大32.6%。综上所述,该微乳液作为压裂液添加剂,可在压裂施工全过程增大原油采出率,具有良好的应用前景。

    Abstract:

    We developed a microemulsion additive for increasing production by imbibition stimulation in low-permeability tight reservoirs, based on the integrated construction method of "compression-injection-recapture" and with the goal of improving the performance of fracturing fluids. The major raw ingredients were anionic surfactant SY-1 and methyl 9-octanoate MS-9, and the phase behavior was explored by fitting a ternary phase diagram and optimizing the formulation using orthogonal tests. The microemulsion's average particle size, according to the results of indoor experiments, is 70.5 nm. It can stabilize under conditions of high-speed centrifugation (8000 rpm) and prolonged standing (180 days); it can reduce the interfacial tension to the order of 10-4-10-3 mN/m; it can reduce the contact angle by approximately 45°; it can maintain the high interfacial activity after 8 adsorptions with the core powder; it has strong anti-sorption ability; it has good compatibility with the fracturing fluid and can enhance the oil washing efficiency by 57~64% during the simulated fracturing entry stage. During the simulated fracturing well stage, the imbibition displacement impact may be raised by 16%, and during the flowback stage, the crude oil recovery rate can be increased by 32.6%. In conclusion, the microemulsion has high application prospects and can be employed as a fracturing fluid additive to boost the crude oil recovery rate throughout the entire fracturing construction process.

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  • 收稿日期: 2023-08-21
  • 最后修改日期: 2024-01-03
  • 录用日期: 2024-01-12
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