石油污染土壤处理新技术--植物型微生物燃料电池的适用性研究
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长江大学武汉校区

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国家自然科学(51474035);国家重点实验室开放课题项(PPC2017005)


Oil contaminated soil treatment new technology-the applicability of the plant type microbial fuel cell research
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    摘要:

    石油在炼制、储运和使用过程中进入土壤并对土壤造成污染,石油污染物危害程度大,处理难度高。现提出植物型微生物燃料电池技术(Plant Microbial Fuel Cell,PMFC)解决这一问题。以受石油污染的土壤为阳极底泥构筑PMFC,通过检测输出电压、功率密度、表观内阻和石油去除率,对电池植物和电极材料进行优选,并用优化后的PMFC探究其石油浓度的适用性和最佳适用范围。结果表明,植物中绿萝在PMFC的厌氧环境中不能成活,而白鹤芋-PMFC的产电性能和降解性能均优于香菇草-PMFC;电极材料中碳毡-PMFC的产电性能和降解性能较碳海绵-PMFC有明显的提升;以白鹤芋为电池植物、碳毡为电极材料的PMFC适用于任一石油浓度,并且随着石油浓度的增加,PMFC的产电性能和降解性能均呈现出先升高后降低的趋势,因此存在最佳石油浓度适用范围5-10g/kg。PMFC技术为石油污染土壤处理提供了一种新的思路,能在有效处理土壤污染问题的同时发电,实现双赢。

    Abstract:

    Oil enters the soil during refining, storage, transportation and use, causing pollution. Oil pollutants are highly harmful and difficult to deal with. Plant Microbial Fuel Cell (PMFC) is proposed to solve this problem. The PMFC was constructed with oil-contaminated soil as anode sludge. By detecting the output voltage, power density, apparent internal resistance and oil removal rate, the battery plants and electrode materials were optimized, and the optimized PMFC was used to explore the oil concentration applicability and optimum scope of application. The results showed that the green dill in plants could not survive in the anaerobic environment of PMFC, while the electricity production and degradation properties of white crane taro-PMFC were better than those of Lentinus edodes-PMFC; Compared with carbon sponge-PMFC, the power generation performance and degradation performance of carbon felt-PMFC in electrode materials are significantly improved; PMFC with white crane taro as battery plant and carbon felt as electrode material is suitable for any oil concentration, and with the increase of oil concentration, the power generation performance and degradation performance of PMFC show a trend of increasing first and then decreasing. So there is an optimal oil concentration range of 5-10g/kg. PMFC technology provides a new idea for oil-contaminated soil treatment, which can effectively deal with soil pollution problems while generating electricity and achieve a win-win situation.

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历史
  • 收稿日期: 2022-07-14
  • 最后修改日期: 2022-09-05
  • 录用日期: 2022-09-26
  • 在线发布日期: 2023-03-20
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