基于原油物性定量表征的油包水乳状液黏度预测模型*
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1.东北石油大学 提高油气采收率教育部重点实验室;2.广东石油化工学院 石油工程学院;3.中国石油大学(华东)

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国家自然科学基金项目“原油-水混合体系的黏度特性研究及基于整合稳定/非稳定态体系的统一黏度预测模型构建”(项目编号52004071),“剪切流场中相间乳化与起泡耦合作用下界/表面膜形成与稳定的影响机制研究”(项目编号52174060);茂名市科技计划项目“原油物性及液滴分散性对原油-水体系黏度特性的影响研究”(项目编号210406224552646),“含蜡原油-矿化水体系的黏度特性研究及乳状液黏度预测模型构建”(项目编号220420204551838)


Viscosity Prediction Model for Water-in-Oil Emulsion Based on Quantitative Characterization of Crude Oil Physical Properties
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Key Laboratory for Enhanced Oil Gas Recovery of the Ministry of Education,Northeast Petroleum University

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    摘要:

    采用8种不同物性的原油制备成油包水乳状液,通过流变仪对乳状液的黏度特性进行测定,研究了温度、含水率及剪切率对油包水乳状液表观黏度的影响。结果表明,油包水乳状液的表观黏度随温度的升高而减小,随含水率的增加而增大,随剪切率的增加而减小,具有剪切稀释性。采用幂率模型来描述油包水乳状液的流变特性,即 ,随着含水率上升,油包水乳状液的稠度系数K逐渐增大,而流变特性指数n逐渐减小;随着温度升高,稠度系数K逐渐减小,而流变特性指数n逐渐增大。以实验数据为基础,并对原油物性进行定量表征,建立了能够适用于不同原油、不同剪切条件的油包水乳状液黏度预测模型。该模型的预测偏差结果显示,模型计算黏度值与实测值之间的平均相对偏差为8.1%。

    Abstract:

    Eight kinds of crude oils with different physical properties were used to prepare water-in-oil (W/O) emulsions. The viscosity characteristics of the W/O emulsions were measured by rheometer. The effects of temperature, water cut of emulsion and shear rate on the apparent viscosity of W/O emulsions were studied. The results show that the apparent viscosity of the W/O emulsion decreases with the increase of temperature, increases with the increase of water cut, and decreases with the increase of shear rate, showing the property of shear thinning. The power law model was used to describe the rheological properties of W/O emulsion, i.e, . With the increase of water cut of emulsion, the consistency coefficient K of W/O emulsion increased gradually, while the rheological property index n decreased gradually. With the increase of temperature, the consistency coefficient K decreased gradually, while the rheological property index n increased gradually. Based on the experimental data and quantitative characterization of crude oil physical properties, a viscosity prediction model for W/O emulsion was established which could be applied to different crude oil and different shear conditions. The prediction deviation of the model shows that the average relative deviation between the calculated viscosity value and the measured viscosity value is 8.1%.

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  • 收稿日期: 2022-07-10
  • 最后修改日期: 2022-08-26
  • 录用日期: 2022-09-08
  • 在线发布日期: 2023-03-15
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