超高相对分子质量两性离子聚合物水溶液的剪切黏度恢复性能
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Shear Viscosity Recovery Performance of Ultrahigh Molecular Weight Zwitterionic Polymer Aqueous Solution
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    摘要:

    针对低渗油藏多孔介质中聚合物剪切黏度损失的问题,以丙烯酰胺 (AM)、2 - 丙烯酰胺基 - 2 - 甲基丙磺酸 (AMPS)、二烯丙基二甲基氯化铵 (DMDAAC) 为主要单体,辅以少量丙烯酸 (AA),采用共聚结合后水解工艺,在 高分子链上同时引入阴阳两性离子基团,制备了黏均相对分子质量达 2138 万的超高相对分子质量两性离子聚合 物 (HSC)。采用红外光谱、核磁共振氢谱对目标四元聚合物结构进行表征,利用自建的恒流毛细管剪切装置,从 聚合物组分与注入速率两方面探讨了剪切黏度恢复性能的影响因素,结合动态光散射 (DLS)、透射电镜 (TEM) 与流变表征分析了聚合物剪切后的黏度恢复过程。结果表明:阴阳离子基团间的可逆相互作用可提高聚合物初 始黏度并赋予其黏弹性能;经毛细管剪切变稀后,高分子链间的离子键合可自行修复,通过重新缔合构建网络结 构,实现黏度的快速恢复;在质量分数 20 % AMPS、0 . 02 % 甲酸铵、0 . 5 % DMDAAC、25 % 水解度条件下制备的聚合 物,剪切黏度恢复性能最佳;在 4500 s-1 的剪切速率条件下,其黏度 1 h 内即可恢复至初始值的 80 % 以上。HSC 具 备良好的剪切黏度自修复能力与耐地层吸附性能,在低渗透油藏深部调驱领域具有较大的应用潜能。

    Abstract:

    To address the problem of shear viscosity loss of polymers in porous media of low-permeability reservoirs,an ultra-high molecular weight zwitterionic polymer (HSC) with viscosity-average molecular weight of 21 . 38 million was prepared via copolymerization of acrylamide (AM),2 -acrylamide- 2 -methylpropanesulfonic acid (AMPS),dimethyl diallyl ammonium chloride (DMDAAC) and a small amount of acrylic acid (AA),followed by post-hydrolysis. Cationic and anionic zwitterionic groups were simultaneously introduced onto the polymer chains. The molecular structure of the target quaternary polymer was characterized by FT-IR and 1H-NMR. The factors affecting shear viscosity recovery performance were investigated from the aspects of polymer composition and injection rate using a self-built constant-flow capillary shear device,and the viscosity recovery process of the sheared polymer was analyzed by DLS,TEM and rheological characterization. The results showed that the reversible attractive interaction between cationic and anionic groups enhanced the initial viscosity of the polymer and endowed it with viscoelastic properties. After shear thinning in capillary,the ionic bonds between polymer chains could be reestablished spontaneously to reconstruct the associated network,enabling rapid viscosity recovery. The polymer prepared with 20 % AMPS,0 . 02 % ammonium formate,0 . 5 % DMDAAC and 25 % hydrolysis degree exhibited the optimal shear viscosity recovery performance. Under a shear rate of 4500 s-1,its viscosity could recover to more than 80 % of the initial value within 1 hour. The excellent shear viscosity self-healing property and resistance to formation adsorption endow HSC with great application potential in deep profile control and flooding for low-permeability reservoirs.

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杨海恩,曾立祥,宋明明,刘云龙,冯笑雅,刘 妍,武宝强,曹 璐,施盟泉.超高相对分子质量两性离子聚合物水溶液的剪切黏度恢复性能[J].油田化学,2026,43(2):297-305.
YANG Haien, ZENG Lixiang, SONG Mingming, LIU Yunlong, FENG Xiaoya, LIU Yan, WU Baoqiang, CAO Lu, SHI Mengquan. Shear Viscosity Recovery Performance of Ultrahigh Molecular Weight Zwitterionic Polymer Aqueous Solution[J]. OILFIELD CHEMISTRY,2026,43(2):297-305.

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