新型微生物聚合物的溶液性能与驱油作用
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国家重点研发计划“油田采油生物制剂研发及应用”(项目编号 2022YFC2105200),中国石化攻关项目“新型微生物杂多糖工 业化发酵及应用”(项目编号224129)


Solution Properties and Oil Displacement of a Novel Microbial Polymer
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    摘要:

    常规合成聚合物 HPAM和黄原胶耐温抗盐性差,在温度≥80 ℃、矿化度≥30 000 mg/L 条件下易降解失黏,且HPAM残余单体易污染环境,难以满足高温、高盐油藏的开发需求。为了适应苛刻油藏环境,开发了一种绿色、高效的新型微生物聚合物FH。采用流变仪重点考察温度、盐度、剪切力和pH值等因素对FH聚合物流变性的影响,同时利用扫描电镜观察不同矿化度下FH聚合物的微观形貌,并评价了FH聚合物的长期热稳定性及驱油效果。研究结果表明,FH溶液、黄原胶溶液和聚合物溶液在受到剪切作用时,黏度均急剧下降,且剪切速度越高,黏度下降越快;当剪切力消除时,FH溶液和黄原胶溶液的黏度分别变为109.3 mPa·s和61.1 mPa·s,黏度恢复率在98%以上,表明FH溶液和黄原胶溶液的剪切变稀现象可逆,具有良好的剪切恢复性。但是HPAM溶液经剪切后,黏度出现不可逆的损失现象。与黄原胶相比,FH聚合物的油藏适应范围广泛,耐受温度可提高20 ℃以上,且在酸性和碱性环境下黏度保持稳定,尤其在高矿化度地层水中可以形成密实的网状结构,增强了环境耐受性。此外,在高温高盐环境中经 40 d老化后,添加含硫有机抗氧剂的FH聚合物长期稳定性较好,黏度保留率达73.6%。物理模拟驱油实验中,注FH聚合物体系(50 g/L FH+0.2%抗氧化剂S)在水驱(采收率 44%左右)基础上提高采收率22个百分点左右,表现出优越的驱油性能,在极端油藏条件下具有广阔的应用前景。

    Abstract:

    Conventional synthetic polymer HPAM and xanthan gum exhibit poor temperature and salt tolerance,being prone to degradation and viscosity loss under high-temperature(≥80℃)and high-salinity(≥30 000 mg/L)conditions,and the residual monomer of HPAM is easy to pollute the environment,which is difficult to meet the development needs of high temperature and high salt reservoirs. To address the demands of harsh reservoir conditions,a new type of green and efficient microbial polymer FH had been developed. The effects of temperature,salinity,shear force and pH value on the rheological properties of FH polymer were investigated using a rheometer. The microstructure of FH polymer under different salinity was observed by scanning electron microscope,and the long-term thermal stability and oil displacement effect of FH polymer were evaluated. The experimental results showed that the viscosity of the FH solution,xanthan gum solution and polymer solution decreased sharply when they were sheared,and the higher the shear rate,the faster the viscosity decreased. When the shear force was eliminated,the viscosity of FH solution and xanthan gum solution became 109.3 mPa·s and 61.1 mPa·s,respectively,and the viscosity recovery rate was above 98%,indicating that the shear thinning phenomenon of the FH solution and xanthan gum solution was reversible and shear recovery was good. However,the viscosity of HPAM solution showed irreversible loss after shearing. Compared with xanthan gum,the FH polymer had a wide range of reservoir adaptability. The temperature resistance could be increased by more than 20 ℃,and the viscosity remained stable in both acidic and alkaline environments. Especially in the high salinity of formation water,the FH biopolymer could form a dense network structure,which enhanced its harsh environmental tolerance. In addition,under the treatment of high temperature and high salt for 40 days,the addition of sulfur-containing organic compound antioxidant could improve the thermal stability of FH biopolymer,and the viscosity retention reached 73.6% . In the physical simulation oil displacement experiment,the injection of the FH polymer system(50 g/L FH +0.2% antioxidant S)enhanced the oil recovery by 22 percentage points based on water flooding(oil recovery being about 44%),which demonstrated superior oil displacement performance and had broad application prospects under extreme reservoir conditions.

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李彩风,曹嫣镔,刘 涛,闫义田,汪卫东,宋永亭,陈琼瑶.新型微生物聚合物的溶液性能与驱油作用[J].油田化学,2026,43(1):165-172.
LI Caifeng, CAO Yanbin, LIU Tao, YAN Yitian, WANG Weidong, SONG Yongting, CHEN Qiongyao. Solution Properties and Oil Displacement of a Novel Microbial Polymer[J]. OILFIELD CHEMISTRY,2026,43(1):165-172.

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  • 在线发布日期: 2026-05-06
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