高盐油藏硅酸钠对聚合物耐盐性的影响
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国家科技重大专项“渤海双高油田多级窜逸堵调驱一体化技术研究及示范”(项目编号2016ZX05058003-010)


Effect of Sodium Silicate on Salt Tolerance of Polymers in High Salinity Reservoirs
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    摘要:

    渤海高盐油藏平均渗透率较大,而普通聚合物的耐盐性较差。为提高普通聚合物耐盐性,增加驱油剂增油降水效果,通过黏度测试和扫描电镜表征,结合物理模拟评价方法,开展了高盐油藏硅酸钠对聚合物耐盐性影响及作用机理研究。研究结果表明,在矿化度为 10 206.6 mg/L 条件下,质量浓度为 2000 mg/L 的普通“高分”聚合物溶液的黏度为 12.4 mPa·s,低于抗盐聚合物溶液的黏度(32.5 mPa·s)。在普通“高分”聚合物溶液中加入硅酸钠可以提高体系的黏度,随硅酸钠浓度增加,“普通聚合物+硅酸钠”复合体系的黏度逐渐增大。在不同的加药方式中,初期“聚合物(2000 mg/L)+硅酸钠(500 mg/L)”体系的黏度(16.8 mPa·s)低于“硅酸钠+聚合物”复合体系的黏度(19.6 mPa·s),但剪切作用后二者黏度相差不大。聚合物分子为网状结构,无机凝胶为絮状结构“,聚合物+硅酸钠”复合体系为骨架更为密集的网状结构。随硅酸钠浓度增大,复合体系的阻力系数增大,残余阻力系数先增大后减小。普通聚合物体系(2000 mg/L)对渗透率约为6000×10-3 μm2岩心的封堵率仅20%,而“聚合物(2000 mg/L)+ 硅酸钠(300 mg/L)”复合体系对渗透率约为6000×10-3 μm2岩心的封堵率高达94.3%。

    Abstract:

    The Bohai high-salinity reservoir exhibits relatively high average permeability,while the salt tolerance of ordinary polymers is poor. In order to enhance the salt tolerance of conventional polymers and improve the oil-increasing and water-reducing effects of flooding agents,the effect of sodium silicate on salt tolerance of polymer in high salt reservoir and its mechanism were studied by viscosity and scanning electron microscope test combined with physical simulation evaluation method. The results indicated that the viscosity of the ordinary polymer solution with a mass concentration of 2000 mg/L was 12.4 mPa s lower than that of the salt-resistant polymer solution(32.5 mPa s)under the condition of salinity of 10 206.6 mg/L. Adding sodium silicate to the ordinary polymer solution could increase the viscosity of the system. As the concentration of sodium silicate increased,the viscosity of the 'ordinary polymer + sodium silicate' composite system gradually increased. In different dosing methods,the viscosity of the initial' polymer(2000 mg/L)+ sodium silicate( 500 mg/L)' system(16.8 mPa·s )was lower than that of the 'sodium silicate + polymer' composite system(19.6 mPa·s). However,their viscosities show little difference after shearing. Polymer molecules formed a network structure,while the inorganic gels exhibited a flocculent structure. The "polymer + sodium silicate" system resulted in a denser network framework. With the increase of sodium silicate concentration,the resistance coefficient of the composite system increased,and the residual resistance coefficient increased first and then decreased. The plugging rate of the ordinary polymer system(2000 mg/L)to the core with a permeability of about 6000×10-3 μm2 was only 20%,while the plugging rate of the 'polymer(2000 mg/L)+ sodium silicate(300 mg/L)' composite system to the core with a permeability of about 6000× 10-3 μm2 was as high as 94.3%.

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刘子龙,卢祥国,何 欣,刘进祥,高建崇.高盐油藏硅酸钠对聚合物耐盐性的影响[J].油田化学,2026,43(1):125-130.
LIU Zilong, LU Xiangguo, HE Xin, LIU Jinxiang, GAO Jianchong. Effect of Sodium Silicate on Salt Tolerance of Polymers in High Salinity Reservoirs[J]. OILFIELD CHEMISTRY,2026,43(1):125-130.

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  • 在线发布日期: 2026-05-06
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