低界面张力抗高钙镁离子减氧空气泡沫体系的制备与性能评价
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延长石油科技项目“低界面张力耐盐型纳米颗粒增稳减氧空气泡沫驱技术研究”(项目编号ycsy2023ky-B-30-01)


Preparation and Performance Evaluation of Low Interfacial Tension Anti-high Calcium and Magnesium Oxygen-reducing Air Foam System
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    摘要:

    针对延长油田长6致密油藏高盐(矿化度≥120 000 mg/L)、高钙镁离子含量(Ca2+含量≥20 000 mg/L、Mg2+ 含量≥400 mg/L)、储层非均质强(渗透率级差=50)条件下注水驱油效果差,含水高(≥75%),采出程度低(14.7%),目前泡沫体系无法适应的难题,在模拟油藏环境条件下,采用高温高压泡沫仪综合评价装置、致密储层渗吸系统测试了8种双子型表面活性剂发泡性能、半衰期、综合泡沫指数,筛选出最佳发泡剂、辅剂及其浓度,构筑了一种低界面张力抗钙镁减氧空气泡沫体系。评价了温度、Ca2+含量、Mg2+含量、含油率及pH值对该体系发泡体积和半衰期的影响,考察了体系在非均质储层驱油效果及渗吸效率规律。研究结果表明,0.4% LY-12(双十二烷羟磺酸盐)+0.1% LX-14(十四烷基氨基酸盐)为最佳泡沫体系,温度、Ca2+含量、含油率、pH值对发泡体积、泡沫半衰期影响大,而Mg2+含量对发泡体积、泡沫半衰期影响较小。当温度≤45 ℃、Ca2+含量≤20 000 mg/L、含油率 ≤30%、pH 为中性条件下可保证最佳泡沫性能,泡沫综合指数≥12 000 mL·min,界面张力为 6.63×10-2 mN/m。当岩心渗透率级差为50 时,非均质储层连续泡沫驱较泡沫段塞后续水驱综合驱油效率提高7%,渗透率为0.96× 10-3 μm2时,渗吸效率达42.88%,在低渗储层中具有很好的适应性。

    Abstract:

    In response to the poor water flooding effect,high water cut(≥75%),low recovery rate(14.7%),in the Chang 6 tight oil reservoir of the Yanchang oilfield,which is characterized by high salinity formation water(≥120 000 mg/L),high calcium and magnesium(Ca2+ content≥20 000 mg/L,Mg2+ content≥400 mg/L),and strong heterogeneity(permeability contrast =50),and the current foam systems' inability to adapt to these conditions,eight Gemini surfactants were evaluated for their foaming performance, half-life,and comprehensive foam index under simulated reservoir conditions using a high-temperature and high-pressure foam instrument and a tight reservoir imbibition system. The best foaming agent,auxiliary agent,and their concentrations were optimized to construct a low interfacial tension,calcium and magnesium resistant,and oxygen-reduced air foam system. The effects of different temperatures,Ca2+ and Mg2+ contents,oil saturation,and pH values on the foaming volume and half-life of the system were evaluated,and the oil displacement efficiency and imbibition efficiency of the system in heterogeneous reservoirs were investigated. The results showed that 0.4% LY-12(dodecyldodecyl hydroxysulfonate)+ 0.1% LX-14(tetradecyl amino acid salt) was the best foam system. Temperature,Ca2 + content,oil content,and pH had a significant impact on the foaming volume and foam half-life,while the effect of Mg2 + content was relatively small. The best foam performance could be guaranteed under conditions of temperature ≤45 ℃,Ca2+ content ≤20 000 mg/L,oil content ≤ 30%,and neutral pH,with a comprehensive foam index ≥12 000 mL min and an interfacial tension of 6.63×10-2 mN/m. When the permeability contrast was 50,the continuous foam flooding in heterogeneous reservoirs had a 7% higher comprehensive oil displacement efficiency than the foam slug followed by water flooding. When the permeability was 0.96×10-3 μm2,the imbibition efficiency reached up to 42.88%,demonstrating good adaptability to low-permeability reservoirs.

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陈龙龙,倪 军,魏登峰,汤瑞佳,尚庆华,马 彬.低界面张力抗高钙镁离子减氧空气泡沫体系的制备与性能评价[J].油田化学,2026,43(1):98-105.
CHEN Longlong, NI Jun, WEI Dengfeng, TANG Ruijia, SHANG Qinghua, MA Bin. Preparation and Performance Evaluation of Low Interfacial Tension Anti-high Calcium and Magnesium Oxygen-reducing Air Foam System[J]. OILFIELD CHEMISTRY,2026,43(1):98-105.

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  • 在线发布日期: 2026-05-06
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