CO2驱蠕虫状胶束泡沫体系构筑及黏弹性研究
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国家重点研发计划“稠油化学复合冷采基础研究与工业示范”(项目编号 2018YFA0702400),山东省自然科学基金“纳米颗粒 稳定乳状液在油藏孔隙介质中形成条件及流度控制机理研究”(项目编号ZR2019MEE085)


Construction and Viscoelastic Characterization of Wormlike Micellar Foam Systems for CO2 Flooding
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    摘要:

    在CO2驱油过程中,气窜现象易导致波及体积减小,从而降低采收率。泡沫驱是抑制CO2气窜的有效方法之一。文章利用阴离子表面活性剂α-烯烃磺酸钠AOS、两性表面活性剂芥酸酰胺丙基甜菜碱EAB及稳泡剂烷基胺TA构建了蠕虫状胶束泡沫体系,并系统研究其黏弹性行为。实验结果表明,配方为0.25% AOS+0.25% EAB+ 0.1% TA的泡沫体系的综合指数可达107 208 mL· min。该体系泡沫性能随温度升高而降低,但在70 ℃以下仍表现出良好的稳定性。黏弹性分析表明,当表面活性剂总质量分数达到0.5%时,AOS与EAB分子相互缠绕形成大量蠕虫状胶束,显著提高体系的体相黏度和黏弹性。蠕虫状胶束结构的高黏弹性可有效延缓液膜排液速率,增强泡沫液膜强度,进而提高泡沫稳定性。

    Abstract:

    Gas channeling during CO2 flooding often reduces sweep efficiency and oil recovery. It is proven that foam injection was effective in controlling CO2 breakthrough. A wormlike micellar foam system was developed using anionic surfactant sodium α-olefin sulfonate(AOS),zwitterionic surfactant erucic acid amide propyl betaine(EAB),and foam stabilizer alkylamine(TA),and its viscoelastic behavior was systematically investigated. The experimental results showed that the comprehensive index of the foam system with the formula of 0.25% AOS + 0.25% EAB + 0.1% TA could reach 107 208 mL· min. While the foam performance decreased with rising temperature,the system maintained good stability below the temperature of 70 ℃. Viscoelastic analysis revealed that at 0.5% total surfactant concentration,AOS and EAB molecules intertwined to form abundant wormlike micelles,as a result,the bulk viscosity and viscoelasticity of the system was significantly improved. The high viscoelasticity of the wormlike micelle structure could effectively retard the liquid film drainage and enhance the strength of the foam liquid film,and thereby improve the foam stability.

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吴宇辉,裴海华,张贵才,刘 杨,马战磊,代汪东. CO2驱蠕虫状胶束泡沫体系构筑及黏弹性研究[J].油田化学,2026,43(1):90-97.
WU Yuhui, PEI Haihua, ZHANG Guicai, LIU Yang, MA Zhanlei, DAI Wangdong. Construction and Viscoelastic Characterization of Wormlike Micellar Foam Systems for CO2 Flooding[J]. OILFIELD CHEMISTRY,2026,43(1):90-97.

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  • 在线发布日期: 2026-05-06
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