量子点驱油剂性能评价及宏观微观驱油特征
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国家自然科学基金项目“致密砂岩油藏CO2吞吐多尺度流、固物性变化机理及对吞吐效果的影响”(项目编号 52174031),国 家自然科学基金项目“VES磨料浆体非牛顿流动及射流冲蚀机理研究”(项目编号 52074220),陕西省自然科学基础研究计划 项目“CO2增强型地热系统干热岩物性演化及其热渗耦合响应机制”(项目编号2024JC-YBMS-367)


Performance Evaluation of Quantum Dot Oil Displacement Agents and Macroscopic and Microscopic Oil Displacement Characteristics
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    摘要:

    为了明确新型C-Si 量子点的基本性能及其在低-超低渗透油藏的适用性,首先对新型C-Si 量子点驱油剂的界面性能和配伍性进行测试分析,然后开展岩心渗吸和驱替实验,探究量子点的宏观渗吸驱油特征,最后借助核磁共振分析和微观模型实验从微观层面揭示量子点的驱油特征。结果表明,量子点驱油剂具有将岩心表面改变为亲水性的能力,同时展现出了较强的负电性以及较好的抗温、抗盐性能。当量子点驱油剂质量分数为0.5%时渗吸驱油效果最佳,渗吸效率可高达48.5%,在岩心驱替过程中展现出了持续效应。量子点粒径小,布朗运动更为剧烈,易进入微小孔隙,在岩心微小孔中的渗吸效率能达到30%,量子点通过对水分子氢键缔合作用的削弱使得水相波及范围增大,可较好地启动绕流残余油、盲端和角隅残余油,研究结果为利用量子点驱油剂提高低-超低渗透油藏的采收率奠定了理论基础。

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    In order to clarify the basic properties of the novel C-Si quantum dots and their applicability in low-ultra-low permeability reservoirs,the interfacial properties and compatibility of the C-Si quantum dot oil displacement agent were tested and analyzed. Subsequently,the core imbibition and displacement experiments were carried out to explore the macroscopic imbibition and displacement characteristics of quantum dots. Finally,the oil displacement characteristics of quantum dots were revealed from the microscopic level by means of nuclear magnetic resonance analysis and microscopic model experiments. The results showed that the quantum dot oil-displacement agent had the ability to change the core surface to hydrophilicity,meanwhile,it exhibited strong negative charge,as well as good temperature and salt resistance. When the concentration of the quantum dot oil-displacement agent was 0.5%,the imbibition oil-displacement effect was the best,and the imbibition efficiency reached as high as 48.5%,showing a continuous effect during the core displacement process. The particle size of quantum dots was small,so the Brownian motion of quantum dots was more intense,and the quantum dots easily entered the micro-pores. The imbibition efficiency of the quantum dots in the micro-pores of the core could reach up to 30%. The quantum dots expanded the sweep range of the water phase by weakening the hydrogen-bond association of water molecules,and could effectively activate bypassed residual oil,dead-end and corner residual oil. The research results lay a theoretical foundation for improving the oil recovery of low and ultra-low permeability reservoirs using the quantum dot oil-displacement agent.

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曹肖怡,罗向荣,陆小兵,闫若勤,任晓娟,程 枫,杨立安,王 磊,陈贝尔.量子点驱油剂性能评价及宏观微观驱油特征[J].油田化学,2026,43(1):70-77.
CAO Xiaoyi, LUO Xiangrong, LU Xiaobing, YAN Ruoqin, REN Xiaojuan, CHENG Feng, YANG Li’an, WANG Lei, CHEN Beier. Performance Evaluation of Quantum Dot Oil Displacement Agents and Macroscopic and Microscopic Oil Displacement Characteristics[J]. OILFIELD CHEMISTRY,2026,43(1):70-77.

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  • 在线发布日期: 2026-05-06
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