加拿大油砂层钻井无机沥青固化剂作用效能及机理
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西安市科技局项目“陕北深层油气钻井用环保寡聚糖-木素聚合物仿生合成与应用”(项目编号 24GXFW0074)


Efficacy and Mechanism of Inorganic Bitumen Curing Agents in Canadian Oil Sands Drilling
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    摘要:

    在加拿大油砂层钻井作业中,油砂中的沥青黏附钻井部件导致的作业效率降低问题亟待解决,但该问题在国内少有钻遇,并无有效解决方案,更无相关评价方案可供借鉴,研究难度极大。文章聚焦沥青固化技术,借鉴无机固化剂高温释放活性氧原子重构油砂组分机制,首次将沥青针入度作为主要性能指标引入本类研究中。选取市售六种典型无机固化剂,将其与加拿大油砂在老化罐中热滚老化,考察了固化前后油砂针入度、模拟钢棒黏附性、钻井液性能。研究结果表明,无机固化剂硫代硫酸钠、无水乙酸钠和过硫酸钾表现出显著固化效能,可使沥青针入度值最高由108/0.1mm降低至25.89/0.1mm并具备长效稳定性,其中,硫代硫酸钠体系在对钢棒的黏附性测试中展现出最优抑制效果,沥青的黏附率由 50.93%显著降至6.71%。此外,油砂固化后对钻井液体系流变性影响较小的同时,会引发滤失量升高及模拟钻具腐蚀等负面效应。通过傅里叶变换红外光谱分析发现,固化剂中的活性离子(如 CH3COO- 、SO42-)与沥青中的极性官能团(—OH、—COOH)发生了化学交联反应;四组分分析发现,固化剂促使沥青组分中低分子量饱和烃与芳香烃向高分子量胶质、沥青质发生了转化,扫描电镜和偏光显微镜分析结果进一步证实,固化后沥青微观结构形成多孔网络状骨架,导致滤饼孔隙率提升,进而加剧了钻井液滤失量的增加。本研究首次揭示了无机固化剂与油砂沥青的作用机制,为解决油砂钻井黏附难题提供了理论依据。

    Abstract:

    In drilling operations of Canadian oil sands,the problem of reduced operational efficiency caused by asphalt adhering to drilling components is urgent to be addressed. However,this issue is rarely encountered domestically,and there are no effective so-lutions or relevant evaluation schemes to draw upon,making the research extremely challenging. This paper focused on asphalt cur-ing technology,drew on the mechanism of inorganic curing agents releasing active oxygen atoms at high temperatures to recon-struct oil sand components. For the first time,asphalt penetration was introduced as the main performance indicator in this study. Six typical commercially available inorganic curing agents were selected and hot-rolled with Canadian oil sands in aging tanks. The penetration of oil sands before and after curing,the adhesion of simulated steel rods,and the influence of drilling fluid performance were investigated. The results indicated that the inorganic curing agent sodium thiosulfate,anhydrous sodium acetate and potassium persulfate showed significant curing efficiency,which reduced the penetration value of asphalt from 108/0.1 mm to 25.89/0.1 mm and had long-term stability. Among them,the sodium thiosulfate system showed the best inhibition effect in the adhesion test of steel rods,and the adhesion rate of asphalt decreased significantly from 50.93% to 6.71%. Furthermore,the solidification of oil sands had little effect on the rheology of the drilling fluid system,but it would cause negative effects such as increased filter loss and simulated drilling tool corrosion. Through Fourier transform infrared spectroscopy analysis,it was found that the active ions in the curing agent,such as CH3COO-,SO42-,had a chemical crosslinking reaction with the polar functional groups in the asphalt, such as —OH,—COOH. Four-component analysis found that the curing agent promoted the conversion of saturated hydrocarbons and aromatic hydrocarbons with low molecular weight in the asphalt component to resins and asphaltenes with high molecular weight. The results of scanning electron microscopy and polarizing optical microscopy further confirmed that the microstructure of the solidified asphalt formed a porous network skeleton,resulting in an increase in the porosity of the filter cake,furtherly aggravat-ed the increase in drilling fluid loss. This study reveals the action mechanism of inorganic curing agent and oil sand asphalt for the first time,and provides a theoretical basis for solving the adhesion problem of oil sand drilling.

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杨 洁,何 萍,耿 铁,樊 靖,都伟超.加拿大油砂层钻井无机沥青固化剂作用效能及机理[J].油田化学,2026,43(1):36-44.
YANG Jie, HE Ping, GENG Tie, FAN Jing, DU Weichao. Efficacy and Mechanism of Inorganic Bitumen Curing Agents in Canadian Oil Sands Drilling[J]. OILFIELD CHEMISTRY,2026,43(1):36-44.

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  • 在线发布日期: 2026-05-06
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