利用多重光散射法评价生物质合成基钻井液的乳状液稳定性
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中国石化集团公司科技攻关项目“生物质合成基液研制”(项目编号 2015201)和“生物质合成基钻井液技术应用研究”(项目 编号 P23211)


Evaluation of Emulsion Stability of Biomass Synthetic-based Drilling Fluids Using Multiple Light Scattering
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    摘要:

    乳状液稳定性是油基、合成基钻井液的核心指标。为深入探究其稳定性机制并优化配方,采用多重光散射法,以生物质合成基钻井液为对象,系统研究了乳化剂类型、有机土加量、乳化剂加量、氯化钙浓度及油水比对其乳状液动态稳定性的影响。通过多重光散射法,结合破乳电压,揭示了各因素对乳状液稳定性的影响规律。结果表明:乳化剂SWRH因与基液 LAE-12 的良好配伍性,表现出最优的稳定效果;有机土加量2.0%、乳化剂加量6%、氯化钙质量分数为40%及油水比不低于75∶25时,乳状液具有较低的不稳定性动力学指数值(TSI)和较小的粒径,稳定性较好。研究还发现,破乳电压法虽便捷,但难以全面反映乳状液动态稳定性及复杂因素影响,而多重光散射法能更直观地揭示乳状液分层、聚结等不稳定机制。本研究结果为生物质合成基钻井液的配方优化提供了理论依据,并提出将多重光散射法与破乳电压法相结合,可构建更全面的乳状液稳定性评价体系,为高性能生物质合成基钻井液的研制与迭代升级提供理论支持。

    Abstract:

    Emulsion stability is a key parameter for oil-based and synthetic-based drilling fluids. To deeply investigate its stability mechanism and optimize formulations,the multiple light scattering method was utilized to systematically examine the effects of emulsifier type,organoclay concentration,emulsifier concentration,calcium chloride concentration,and oil-to-water ratio on the dynamic stability of a biomass synthetic-based drilling fluid. By combining multiple light scattering with electrical stability(ES) tests,the influence of each factor on emulsion stability was determined. The results showed that the emulsifier SWRH demonstrated optimal stabilizing effects due to its excellent compatibility with the LAE-12 base fluid. The emulsion exhibited better stability,was characterized by a lower turbiscan stability index (TSI) value and smaller particle size,under the following conditions:an organoclay concentration of 2.0%,an emulsifier concentration of 6%,a calcium chloride concentration of 40%,and an oil-to-water ratio no lower than 75∶25. The study also found that while the electrical stability test is convenient,it cannot comprehensively reflect the dynamic stability of the emulsion or the influence of complex factors. In contrast,the multiple light scattering method can more intuitively reveal instability mechanisms such as creaming and coalescence. The findings of this research provide a theoretical basis for the formulation optimization of biomass synthetic-based drilling fluids. It is proposed that combining multiple light scattering with electrical stability tests can establish a more comprehensive evaluation system for emulsion stability,offering theoretical support for the development and iterative improvement of high-performance biomass synthetic-based drilling fluids.

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张 弌,单海霞,赵田田,位 华,周启成.利用多重光散射法评价生物质合成基钻井液的乳状液稳定性[J].油田化学,2026,43(1):18-26.
ZHANG Yi, SHAN Haixia, ZHAO Tiantian, WEI Hua, ZHOU Qicheng. Evaluation of Emulsion Stability of Biomass Synthetic-based Drilling Fluids Using Multiple Light Scattering[J]. OILFIELD CHEMISTRY,2026,43(1):18-26.

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  • 在线发布日期: 2026-05-06
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