地面管网含硫酸性腐蚀环境用缓蚀剂的性能与作用机制
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中国石油化工股份有限公司科技项目“高含硫油藏开发安全保障关键技术研究”(项目编号 321034)


Performance and Action Mechanism of Corrosion Inhibitors Used in Sulfuric Acid Corrosive Environment of Ground Pipe Network
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    摘要:

    为了改善地面管网含硫酸性高温环境的腐蚀问题,用微波法合成了一种N掺杂碳点缓蚀剂NCDs,采用电化学和失重法测试了NCDs在25、60、90 ℃下对N80 钢片在模拟溶液中的缓蚀作用。结果表明,在相同NCDs浓度下,随温度的升高,缓蚀效率降低。在25 ℃下,缓蚀剂NCDs质量浓度为150 mg/L 时的缓蚀效率达到最大,达94.16%;在 60 ℃下,NCDs 质量浓度为 200 mg/L 时的缓蚀效率最大,为 82.92%;在 90 ℃下,NCDs 质量浓度为150 mg/L 时缓蚀效率达到 69.59%。对腐蚀形貌分析发现 90 ℃时,钢片表面的腐蚀坑深度和数目最多。吸附等温曲线表明,NCDs 在 90 ℃时吸附平衡常数最大,但高温会使其局部腐蚀更严重。此外发现N掺杂碳点的吸附类型为物理与化学混合吸附。该碳点缓蚀剂可有效解决地面管道高温下的腐蚀,延长使用寿命。

    Abstract:

    An N-doped carbon dots corrosion inhibitor was synthesized by microwave method to improve the corrosion problem of ground pipe network under sulfur-containing acidic high-temperature environment. Its corrosion inhibition effect on N80 carbon steel in simulated solution at 25 ℃,60 ℃ and 90 ℃ was tested by electrochemical and weight loss methods. The results showed that the efficiency of corrosion inhibitor(ECI)increased with the increase of the temperature. The ECI reached the maximum of 94.16% at the temperature of 25 ℃ at the NCDs dosage of 150 mg/L. The maximum was 82.92% at the temperature of 60 ℃ at the NCDs dosage of 200 mg/L. At the temperature of 90 ℃ and at the NCDs dosage of 150 mg/L,it reached up to 69.59%. The analysis of corrosion morphology showed that the depth and number of corrosion pits on the steel were the largest at the temperature of 90 ℃. The adsorption isotherm curve showed that the adsorption equilibrium constant of NCDs was the largest at 90 ℃,but the local corrosion was more serious at high temperature. In addition,it is found that the adsorption type of N-doped carbon dots was physical and chemical mixed adsorption. The carbon dots corrosion inhibitor could effectively solve the corrosion of ground pipelines at high temperature and prolong the service life.

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李 薛,孙振华,周海刚,魏 旭,周兆院,刘晶姝.地面管网含硫酸性腐蚀环境用缓蚀剂的性能与作用机制[J].油田化学,2023,40(3):509-515.
LI Xue, SUN Zhenhua, ZHOU Haigang, WEI Xu, ZHOU Zhaoyuan, LIU Jingshu. Performance and Action Mechanism of Corrosion Inhibitors Used in Sulfuric Acid Corrosive Environment of Ground Pipe Network[J]. OILFIELD CHEMISTRY,2023,40(3):509-515.

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  • 收稿日期:2023-03-31
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  • 在线发布日期: 2023-11-07
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