强乳化复合表面活性剂驱油体系研究与应用
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中国石油天然气股份有限公司长庆油田分公司科研项目“CO2捕集,驱油与埋存技术示范工程”(项目编号2016ZX05056)


Study and Application of Strong Emulsion Composite Surfactant Flooding System
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    摘要:

    表面活性剂的乳化能力强弱对提高低渗透油藏水驱开发后的驱油效果影响较大,为了增强表面活性剂驱 油体系的乳化性能、提高驱油效率,将具有良好界面活性的阴-非双子表面活性剂GEY-2 和具有较强乳化能力的 非离子表面活性剂6501 复配,研制出了一种适合低渗透油藏的强乳化复合表面活性剂驱油体系,并对其综合性 能进行了评价。结果表明:强乳化复合表面活性剂驱油体系具有良好的耐温性能和耐盐性能,在高温高矿化度 条件下,配方为2000 mg/L GEY-2+3000 mg/L 6501 的驱油体系仍能保持10-3mN/m超低数量级的油水界面张力, 该驱油体系与储层原油按照7∶3 所形成乳状液在75 ℃下放置10 min 和100 min 后的乳化水率仍能达到90.2%和 61.2%,具有较高的乳化性能。该驱油体系具有良好的抗吸附性能,可以减少驱油剂的浪费,有效保证驱油效 果。该驱油体系对低渗透岩心的驱油效果较好,当岩心渗透率为11.38×10-3 μm2时,水驱结束后注入0.5 PV强乳 化复合表面活性剂驱油体系可使采收率继续提高20%以上。现场应用结果表明,H油田低渗区块实施强乳化复 合表面活性剂驱油措施后,注入井压力有所升高,对应油井日产油量从措施前的2.20 t 升至5.41 t,平均含水率从 措施前的89.2%降低至71.5%,达到了较好的增油效果。

    Abstract:

    The emulsifying ability of surfactant has a great impact on improving the oil displacement effect after water flooding development of low-permeability reservoir. In order to enhance the emulsifying performance of surfactant oil displacement system and improve oil displacement efficiency,anion non Gemini surfactant GEY-2 with good interfacial activity and non-ionic surfactant 6501 with strong emulsifying ability were combined,a strong emulsion composite surfactant flooding system suitable for low permeability reservoir was developed,and its comprehensive performance was evaluated. The results showed that the strong emulsifying composite surfactant oil displacement system had good temperature resistance and salt resistance. Under the conditions of high temperature and high salinity,the oil displacement system composed of 2000 mg/L GEY-2 and 3000 mg/L 6501 could still maintain urtralow oil-water interfacial tension,being of 10-3 mN/m. The emulsified water rate of the elusions,which was formed through combing the composite surfactant oil displacement system with the crude oil in volume ratio of 7∶3,was 90.2% and 61.2% after placed at the temperature of75 ℃ for 10 min and 100 min,respectively,which indicating the system had strong emulsifying property. The system had good anti-adsorption performance,which could reduce the waste of oil displacement agent and effectively ensure the oil displacement effect. The composite surfactant flooding system had a good oil displacement effect on low-permeability cores. When the core permeability was 11.38×10-3 μm2,the oil recovery could be enhenced by more than 20% by injecting 0.5 PV strong emulsion composite surfactant flooding system after water flooding. The field application results showed that after the implementation of strong emulsion composite surfactant displacement measures in the low permeability block of H oilfield,the injection well pressure increased,the daily oil production of corresponding oil wells increased from 2.20 t to 5.41 t,and the average water cut decreased from 89.2% to 71.5%,which achieved a good oil increase effect.

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易凡,陈龙,师涛,姚惠敏.强乳化复合表面活性剂驱油体系研究与应用[J].油田化学,2022,39(3):466-473.
YI Fan, CHEN Long, SHI Tao, YAO Huimin. Study and Application of Strong Emulsion Composite Surfactant Flooding System[J]. OILFIELD CHEMISTRY,2022,39(3):466-473.

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  • 在线发布日期: 2022-10-20
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