深层页岩气压裂用高黏高降阻一体化稠化剂的制备与性能评价
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中国石化科技攻关项目“深层页岩气高导流复杂缝网压裂关键技术”(项目编号P20046-3),高分子材料工程国家重点实验室开放基金探索项目“页岩气开采用智能高分子材料的研究”(项目编号sklpme2014-2-06)


Preparation and Performance Evaluation of Integrated Thickener with High Viscosity and High Drag Reduction Used for Fracturing Deeper Shale Gas
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    摘要:

    滑溜水水力压裂是高效开发页岩气的重要方法,但存在黏度低、淡水用量大和胶液不可自由转换等系列问题,限制了其在3500 m以深的深层页岩气中的应用。为解决上述问题,以丙烯酰胺、2-丙烯酰胺基-2-甲基丙磺酸等为原料,通过自由基聚合反应,室内合成了高黏高降阻一体化稠化剂(HVFR),考察了其溶解性、增黏性、降阻性、携砂性及耐温耐剪切性。结果表明,HVFR的相对分子质量为22.7×106。HVFR溶解速率快,1 min 增黏率达到93%,有利于实现压裂液的在线连续混配。HVFR的降阻性能良好。在150 L/min 流量下,作为低黏、高黏滑溜水时的降阻率均大于70%,作为胶液时的降阻率可达到68%。HVFR具有一剂多能特性,通过调整其浓度可实现低黏滑溜水、高黏滑溜水和胶液之间的自由转换。基于HVFR的交联压裂液具有良好的携砂能力及耐温耐剪切性能。在120 ℃、170 s-1下剪切120 min后,压裂液的保留黏度约为120 mPa·s,满足压裂施工的要求。

    Abstract:

    Slick water hydrofracking is an important method for the efficient development of shale gas,but there are a series of challenges such as low viscosity,large freshwater consumption and slick water-to-gel transition,which limit its application on the hydrofracking of deeper(>3500 m)shale gas reservoirs. In order to solve these problems,an integrated thickener(HVFR)with high viscosity and drag reduction was synthesized by free radical polymerization of acrylamide and 2-acrylamido-2- methylpropanesulphonic acid. The solubility,thickening ability,drag reduction,proppant carrying capability and temperature and shear resistance of HVFR were studied. The results showed that the relative molecular mass of HVFR was 22.7 × 106. HVFR thickener exhibited a rapid dissolution rate with thickening rate of 93% within 1 min,which was conducive to the online continuous mixing of fracturing fluid. HVFR thickener exhibited significant drag reduction performance. At a flow rate of 150 L/min,the drag reduction of slick water was higher than 70% for both low and high viscosity,and that was up to 68% for gel. HVFR thickener exhibited multifunctional properties and could be freely transited between slick water with low and high viscosity and gel by altering the concentration of HVFR. The cross-linked fracturing fluid based on HVFR displayed not only remarkable temperature and shear resistance,but also good proppant carrying capacity. The viscosity of cross-linked fracturing fluid could be maintained about 120 mPa·s after shearing 120 min at 120 ℃ and 170 s-1,which met the requirement of fracturing operation.

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魏娟明,贾文峰,陈昊,冯玉军.深层页岩气压裂用高黏高降阻一体化稠化剂的制备与性能评价[J].油田化学,2022,39(2):234-238.
WEI Juanming, JIAWenfeng, CHEN Hao, FENG Yujun. Preparation and Performance Evaluation of Integrated Thickener with High Viscosity and High Drag Reduction Used for Fracturing Deeper Shale Gas[J]. OILFIELD CHEMISTRY,2022,39(2):234-238.

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  • 在线发布日期: 2022-07-20
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