自生热体系对压裂液破胶性能的影响*
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国家自然科学基金重大项目“井筒工作液与天然气水合物储层作用机理和调控方法”(项目编号51991361),国家自然科学基 金青年科学基金项目“钻探天然气水合物中井壁稳定性及钻井液低温流变性的控制方法研究”(项目编号ZX20140175),中 国石油大学(北京)科研基金“复杂油气田地质与提高采收率技术-复杂结构井优化设计与控制关键技术-复杂结构井储层损 害评价与保护技术”(项目编号ZX20090348)


Effect of Autogenous Heat Generation System on Gel Breaking Performance of Fracturing Fluid
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    摘要:

    针对浅层低温油气井压裂后压裂液破胶不彻底、返排率低的问题,优选了亚硝酸盐与铵盐、三氧化铬和葡 萄糖、过氧化氢3种自生热体系的最佳反应参数,分析了3种自生热体系的生热量以及对压裂液破胶性能的影 响。结果表明,硝酸盐与铵盐自生热体系的最佳反应参数为激活剂HCl浓度2 mol/L,生热剂NaNO2和NH4Cl(物 质的量比1∶1)浓度为8 mol/L;三氧化铬和葡萄糖自生热体系的最佳反应参数为激活剂HCl浓度1 mol/L,生热剂 CrO3和C6H12O6(质量比1∶1)加量为14%;过氧化氢自生热体系的最佳反应参数为激活剂MnO2加量0.3%,生热剂 H2O2加量为30%。过氧化氢自生热体系的生热量最高,温度可达到91 ℃。在压裂液破胶实验中,葡萄糖和三氧 化铬自生热体系和破胶剂过硫酸铵的加入顺序对压裂液的破胶效果无影响,过氧化氢自生热体系应和破胶剂同 时加入,亚硝酸盐与铵盐自生热体系的加入顺序为先加入自生热体系后加入破胶剂。亚硝酸盐与铵盐自生热体 系是压裂液破胶体系的最佳添加剂,可使压裂液黏度降至6 mPa·s以下,破胶性能最优。

    Abstract:

    Aiming at the problems of incomplete gel breaking and low flowback rate of fracturing fluid after fracturing in shallow low-temperature oil and gas well,the optimum reaction parameters of three autogenous heat generation systems,including nitrite and ammonium salt,chromium trioxide and glucose,and hydrogen peroxide were selected. Under the reaction parameters,the heat generation of three systems and their influence on gel breaking performance of fracturing fluid were analyzed. The results showed that the best reaction parameter for nitrate and ammonium salt system was obtained as follows:2 mol/L activator HCl,8 mol/L heat generating agent NaNO2 and NH4Cl(molar ratio 1∶1). That for chromium trioxide and glucose system was obtained as follows:1mol/L activator HCl,14% heat generating agent CrO3 and C6H12O6(mass ratio 1∶1). That for hydrogen peroxide system was obtained as follows:0.3% activator MnO2,30% heat generating agent H2O2. Hydrogen peroxide system had the highest heat generation,and the temperature could reach 91 ℃. In the gel breaking experiment of fracturing fluid,the adding sequence of glucose and chromium trioxide system and gel breaker ammonium persulfate had no influence on gel breaking effect of fracturing fluid. The hydrogen peroxide system should be added with gel breaker at the same time. However,for the nitrite and ammonium salt system,the gel breaker was added after the heat generation system. The nitrite and ammonium salt system was the best additive for gel breaking system of fracturing fluid and had the best gel breaking performance,which could reduce the viscosity of fracturing fluid to less than 6 mPa·s.

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沈秀伦,蒋官澄,李新亮,甄延忠,崔凯潇,李武泉.自生热体系对压裂液破胶性能的影响*[J].油田化学,2021,38(4):620-626.
SHEN Xiulun, JIANG Guancheng, LI Xinliang, ZHEN Yanzhong, CUI Kaixiao, LI Wuquan. Effect of Autogenous Heat Generation System on Gel Breaking Performance of Fracturing Fluid[J]. OILFIELD CHEMISTRY,2021,38(4):620-626.

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  • 在线发布日期: 2022-01-29
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